银纳米颗粒对正渗透膜有机污染的影响机制-环境工程生大学论文.docVIP

编号 本科生毕业设计（论文） 题目：银纳米颗粒对正渗透膜有机污染的 影响机制 环境与土木工程 学院 环境工程 专业 学 号 1003110106 学生姓名 xx 指导教师 xx 副教授 二〇一五年六月 摘 要 正渗透（FO）是一种新兴的膜分离技术，由于不需要外加压力，能耗低出水好等优点，正受到越来越多的关注也不可避免地存在膜污染的问题银纳米颗粒(Ag NPs)由于独特的物理化学性质得到广泛应用，在抗菌杀毒方面是最有前景的金属纳米颗粒之一构建FO过滤装置，Ag NPs时FO膜的污染情况，并重点分析了Ag NPs对FO膜有机污染的影响机制. 结果表明，复合薄膜TFC较醋酸纤维膜CTA整体表现出的运行性能：高通量，低反向盐渗透在特征有机物对FO膜污染中发现，相对来说，TFC膜、FO朝向下的BSAALG混合溶液的通量小，电导率差大；而CTA膜、PRO朝向下的BSA溶液的通量大，电导率差小Ag NPs对FO膜的污染实验表明，在添加5 mg/L的Ag NPs时，CTA膜和TFC膜通量均小于1 mg/L Ag NPs在添加Ag NPs后，膜面的污染情况加重，并且Ag NPs浓度越高，污染程度越大，而且TFC膜的污染情况较CTA膜更严重在Ag NPs对膜污染中发现添加1 mg/L Ag NPs后，通量在开始时稍微下降，Ag NPs的对照组.这表明银纳米颗粒对有机污染物有的影响且Ag NPs对有机污染物起到减缓作用添加2 mg/L的Ag NPs添加1 mg/L Ag NPs 关键词：ABSTRACT Forward osmosis (FO) is a new membrane separation technology, since it does not require external pressure and need lower energy consumption. Thus, it attracts more and more interests. However, FO process inevitably exists a problem of membrane fouling. Silver nanoparticles(Ag NPs) is widely used due to its unique physical and chemical properties and ,it is one of the most promising metal nanoparticles in the aspect of antibacterial and virus. By design and operate the FO filtration device, we can investigate the pollution in FO membrane by only organic matter(ALG and BSA) or Ag NPs in blank experiment, and focus on the influence of FO membrane fouling by Ag NPs. The results indicated that compared to cellulose acetate membrane(CTA), thin-film composite polyamide (TFC) has better operation performance including higher flux and lower reverse osmotic salt. With regard to the study on the influence of feature organic foulants on the FO membrane fouling, it could be found that in the situation of using the TFC membrane, BSAALG solution and AL-FW had a lower flux, a bigger electric conductivity difference and a more serious pollution. In contrast, when the CTA membrane was applied, BSA solution and AL-DS had a higher flux ,