高分子物理部分(国外英语资料).docVIP

高分子物理部分 Polymer physics 1. Compare the definitions, physical meanings and determination methods of the following physical parameters. (15 points) (1) melting point and equilibrium melting point; (2) number average molecular weight and weight average molecular weight; (3) crystallinity and orientation degree; (4) mean square end-to-end distance and mean square radius of gyration; (5) elastic modulus and zero shear viscosity; Two. Briefly describe the mechanical properties of rubber elasticity and explain the reasons for its elasticity. (6 points) Three, what is the Gauss chain? Whats the difference between a Gauss chain and a free link chain? (4 points) Four. How many kinds of energy dissipation are there in a polymer sample from force to full failure? Which way is the most energy dissipation? (5 points) Five. Draw the phase diagram of two yuan high polymer alloy, discuss the physical meaning of each curve in the phase diagram, and the phase separation mechanism of each region. If the compatibility between the two polymers is very poor, what methods can be used to increase their compatibility, and a specific polymer system example will be used to illustrate them. (5 points) Six. Mapping the effects of molecular weight of polymers on the following properties: (10) A, modulus temperature behavior, B, melt viscosity, C, glass transition temperature, D, tensile strength, e and crystallization speed. Seven. At a temperature of Tg=-17 DEG C at a temperature of 25 DEG C, it takes 8 hours to relax the stress to a modulus of 2 * 105N/m2, and to test how long it will take to relax at the -20 temperature to the same modulus (5 points) Polymer Chemistry Section Fill in the blanks (20 minutes) 1, from the analysis of polymerization thermodynamics, heat polymerization of ethylene isobutene (Gao Huodi), the reason is hotter than ethylene polymerization; styrene (Gao Huodi), the reason is two; partial polymerization of vinyl chloride ethylene polymerization heat heat (Gao Huodi), t