水热碱蚀与碱溶滤联合处理制备介孔丝光沸石 - ingenta connect.pdf

See discussions, stats, and author profiles for this publication at: /publication/263266610 Mesoporous Mordenites Obtained by Sequential Hydrothermal Alkaline Etching and Alkaline Leaching Treatments Article in Kuei Suan Jen sueh Pao/ Journal of the Chinese Ceramic Society · January 2013 DOI: 10.7521/j.issn.0454–5648.2013.09.06 CITATION READS 1 26 5 authors, including: Yingjie Jin Liaoning Shi ua University 23 PUBLICATIONS 105 CITATIONS SEE PROFILE All content following this page was uploaded by Yingjie Jin on 01 April 2016. The user has requested enhancement of the downloaded file. All in-text references underlined in blue are added to the original document and are linked to publications on ResearchGate, letting you access and read them immediately. · 1198 · 硅 酸 盐 学 报 2013 年 第41 卷第9 期 硅 酸 盐 学 报 Vol. 41 ，No. 9 2 0 1 3 年 9 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY September，2013 DOI ：10.7521/j.issn.0454–5648.2013.09.06 水热碱蚀与碱溶滤联合处理制备介孔丝光沸石 1 2 1 1 1,2 杜夏梅 ，谷迎秋 ，孙月桥 ，徐丽颖 ，金英杰 (1. 辽宁石油化工大学化学与材料科学学院；2. 辽宁石油化工大学石油化工学院，辽宁 抚顺 113001) 摘 要：以硅酸钠溶胶和铝酸钠为硅、铝源，采用水热合成和离子交换法制备了质子型丝光沸石(H-MOR) 。研究水热碱蚀与碱溶滤联合处理对H-MOR 改性样品的介孔结构、晶体形貌、组成及酸性质的影响。结果表明：用初始浸渍液对H-MOR 进行水热碱蚀，H-MOR 骨架脱硅选择性高，晶体含有 均一的筛状介孔；水热碱蚀与一次碱溶滤处理的样品具有尺度分布较窄的槽形介孔，沸石骨架硅铝比降低而介孔率增加；再度进行碱溶滤处理，沸石 的最可几介孔尺寸和累计介孔体积进一步增大，