超声与微波条件下Ce4+对柴油氧化脱硫的比较研究 - 化学通报.PDFVIP

《化学通报》在线预览版 超声与微波条件下 Ce4+对柴油氧化脱硫的比较研究 马 洁 王长水 张秀兰 周生学 (首都师范大学化学系， 北京 100037) 摘要 分别在超声和微波条件下使用 Ce4+把柴油中的硫化物(主要为苯并噻吩类)氧化成砜类化合物后，再用 DMF 把它萃取 除去。超声条件下的氧化脱硫达到 95.5 ％的高脱硫率，达到世界燃料规范Ⅲ柴油质量标准。微波条件下的氧化脱硫达到82.7 ％的脱硫率。Ce4+氧化媒质可以经电化学方法再生循环利用，DMF 也可以循环利用，无三废排放，具有优化的经济效益比， 符合绿色化学发展的趋势。 关键词 氧化脱硫 Ce(SO ) 柴油 二苯并噻吩(DBT) 二苯并噻吩砜(DBTO ) 4 2 2 4+ Oxidative Desulfurization of Diesel Fuel in Ce Medium under Supersonic and Microwave Ma Jie, Wang Changshui, Zhang xiulan, Zhou Shengxue ( Department of Chemistry, Capital Normal University, Beijing 100037) Abstract Under supersonic and microwave condition sulfur compounds (such as the benzothiophene mainly) in diesel fuel can be oxidized to sulfone by Ce4+ medium, then it can be removed by using extraction of DMF. Under supersonic condition sulfur content in diesel fuel is reduced from 554 ppm to 25 ppm, i.e. 95.5 ％ desulfurization ratio has been achieved the sulfur content of diesel oil after oxidization has met to the quality standard of diesel oil in World Fuel standard Ⅲ. Under microwave condition sulfur content in diesel fuel is reduced from 554ppm to 96ppm, the desulfurization ratio is up to 82.7 ％. The used Ce4+ oxidation medium and solvent can be regenerated and recycled. Due to no wastes to discard in the desulfurization, so these two methods are both accordance with the trend of development of green chemistry. Key words Oxidative desulfurization, Ce(SO ) , Diesel fuel, Dibenzothiophene(DBT), Dibenzothiophene sulfonea(DBTO ) 4 2 2