鸡粪制备的生物碳对水中磷的吸附去除研究.pdfVIP

胡辈革等 鸡羹制备的生物碳对水~i码的吸附去除研究 鸡粪制备的生物碳对水中磷的吸附去除研究 胡菲菲1 邵庆国z (1.长江大学城市建设学院，湖北荆州 434023;2. 华港燃气集团有限公司.精北 沧州 061000) 摘要 以鸡粪为原料热解制备的生物碳作为吸附剂，考察了水中磷在生物碳上的吸附动力学，以及吸附效果的主要影响因 素，并对磷的去除机制做了初步探讨.结果表明g 以鸡粪为原料制备的生物碳具有较高的灰分含量和较高的比表面积，这有利于其 对哥哥的吸附s 拟一级动力学模型能更好描述水中确在生物碳表面的吸附行为，水中确是通过吸附到生物碳表面的胶体和 MgO颗粒 上而得以去除的3 磷在生物碳上的吸附等温线能被好用 Freundlich、Langmuir-Freundlîch 模型来拟合，表明生物碳对哥哥的吸附是由 非均质过程控制的s 生物碳对确的吸附作用受溶液 pH 的影响，这是由于 pH 影响盟军液中磷的存在形式，而各种离子在生物碳表 面的竞争吸附会影响确的吸附效果s 利用鸡粪热解产生的生物碳吸附去除水中磷是可行的，不仅成本低廉并且能够达到以废治 废的目的. 关键词鸡粪生物碳除磷吸附动力学吸附等温线 Study OD the adsorptioD or phosphate iD aquω因ω，IUtlOD by biochar derived rrom chicken manure HU Feifei 1 .SHAO 2 Qingguo • (1. School of City Constructíon. Yangtu UniVersity , ] ingzhou Hubei 434023; 2. Huagang Gas Group Co. • Ltd. , Cangzhou Hebei 061000) Abstract: The biochar prepared from pyrolysis of chicken manure was used as sorbent to removal phosphate in aqueous solution. The kinetics. influence factors and mechanism of phosphate adsorption was preliminary discussed in this paper. The results showed that the obtained biochar had the property of high ash content and high specific surface area. which was benefit for phosphate adsorption. The pseudo first-order kinetics could better describe the dynamic behavior of phosphate adsorption on surface of biochar. The preliminary adsorption mechanism of phosphate removal was adsorption onto the colloidal and nano- sized MgO particles on biochar surface. Freundlich and Langmuir-Freundl- ich models fitted the adsorption isotherm hetter than Langmuir adsorption model , proved the heterogeneous process of phosphate adsorption. pH had significant effect on the adsorption process because it could influence the form of phos- p