生物质催化气化制取富氢燃气的研究 - 中国变压吸附设备商务网.pdfVIP

第 4 卷第 11 期 环境污染治理技术与设备 Vol . 4 ,No . 11 2 0 0 3 年 1 1 月 Techniques and Equipment for Environmental Pollution Control Nov . 2 0 0 3 生物质催化气化制取富氢燃气的研究 吕鹏梅　熊祖鸿　常　杰　付　严　陈　勇 ( 中国科学院广州能源研究所 , 广州 510070) 摘 　要 　以流化床为反应器,探讨了一些主要参数如 :反应器温度 ,水蒸气 ,当量比 ER 以及催化剂对气体成分、氢产率 ( 和潜在氢产率的影响。实验所用催化剂为白云石和镍基催化剂。在实验条件范围内 ,氢产率为 22 —83 g/ kg 生物质 湿 ) ( ) 基 , 潜在氢产率为 115 —223 g/ kg 生物质 湿基 。结果表明 ,较高的反应器温度 ,适当的水蒸气添加量可以有效提高氢的 产出 ; 白云石和镍基催化剂可使产品气中的氢含量提高10 %以上。 关键词 　生物质 　催化气化 　制氢 Potential of hydrogen production from biomass catalytic gasification Lu Pengmei 　Xiong Zuhong 　Chang Jie 　Fu Yan 　Chen Yong ( Guangzhou Institute of Energy Conversion , Chinese Academy of Sciences , Guangzhou 510070) Abstract 　Parametric experiments were performed in a fluidized bed to determine the effects of reaction tempera ture , steam , equivalence ratio ( ER) and catalysts on gas composition , hydrogen and potential hydrogen yield. The catalysts used were dolomites and nickelbased catalysts and were located in gasifier and a downstream fixed reactor , respectively. Of the conditions tested , hydrogen yield ranges between 22 and 83 g per kg of biomass (wet basis) and hydrogen yield potential ranges between 115 and 223 g per kg of biomass (wet basis) . The experimental results prove that higher reaction temperature , proper steam quantity and ER will contribute to more hydrogen production. Hydrogen concentration of gaseous product can be increased over 10 % through the use of dolomite and nickelbased catalysts. Key words 　biomass ; catalytic gasification ; hydrogen