聚酰胺酸薄膜表面热亚胺化动力学研究-高校化学工程学报.PDF

第23 卷第5 期 高 校 化 学 工 程 学 报 No.5 Vol.23 2009 年10 月 Journal of Chemical Engineering of Chinese Universities Oct. 2009 文章编号：1003-9015(2009)05-0796-05 聚酰胺酸薄膜表面热亚胺化动力学研究 王少峰, 朱梦冰, 蒋远媛, 王朋朋, 黄 培 (南京工业大学 化学化工学院 材料化学工程国家重点实验室, 江苏 南京 210009) 摘 要：采用均苯四甲酸二酐(PMDA)与 4,4’-二氨基二苯醚(ODA)为单体，聚合得到表观黏度为 1800 mPa⋅s 的聚酰胺 酸(PAA) ；通过衰减全发射红外光谱(ATR-FTIR)对聚酰胺酸凝胶膜表面亚胺化动力学进行了研究，结果表明：亚胺化 程度随时间的增加和温度的升高而增大，并出现初期的快速和后期的慢速两个阶段。此外，由于薄膜下表面含有较多 的残留溶剂，使其酰亚胺化程度高于上表面。用两步一级动力学模型进行关联，得到了相关的动力学参数。 关键词：聚酰胺酸；衰减全反射红外光谱；亚胺化；动力学 中图分类号：TQ322.3 ；TQ323.7 文献标识码：A Kinetic Study of the Thermal Imidization for Poly(amic acid) Film WANG Shao-feng, ZHU Meng-bing, JANG Yuan-yuan, WANG Peng-peng, HUANG Pei (State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China) Abstract: Via polymerization of pyromellitic dianhydride (PMDA) and 4,4′-diamino diphenyl ether (ODA), the poly(amic acid) with apparent viscosity of 1800 mPa·s was obtained. The imidization kinetics of the poly(amic acid) film surface was studied by ATR-FTIR spectrometry. The results indicate that the degree of imidization increases with the increase of time and temperature, while the imidization is characterized by a fast initial step and a slow latter step. Additionally, a higher degree of imidization occurs on the bottom surface of the film because there is a higher retention of solvent on it. Moreover, the relevant kinetic parameters were obtained through correlating the data of imidization degree vs. time by a two-step first-