NiNb 粉末与SiC陶瓷界面润湿特性研究 - 武汉理工大学学报.PDF

28 5 武 汉 理 工 大 学 学 报 Vol. 28 No. 5 2006 5 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY May 2006 NiNb SiC 1 2 张 利 , 李树杰 ( 1. , 101601;2., 100083) : 研究了Ni Nb 金属粉末与SiC 陶瓷的界面润湿特性, 结果表明, 增加Nb 含量升高温度或延 保温时间, 系统 润湿性均得到改善对润湿系统界面区域微观结构的 SEMEDS 分析表明, 由于活性元素Nb 的加入, 在 一定的温度时 间和气氛等条件下, 焊料与陶瓷发生相互间的溶解扩散和反应,其接触界面发生改变, 此时测得的润湿角已不是Ni Nb 液滴/ SiC 陶瓷衬底的接触角, 而是新生成的固液界面间的接触角界面区域具有连续结构的 Ni Si 化合物的生成对于 Ni Nb/ SiC 陶瓷体系的润湿起重要作用 : 化学润湿; 接触角; 动力学; SiC 陶瓷 : TQ 174 : :2006 Investigation on the Wettability etween NiNb Powders and SiCCeramic 1 2 ZHA N G L i , L I Shuj ie ( 1.Department of rchitectural Engineering, North China Institute of Science and Technology, Yanjiao 101601, China; 2.Department of Materials Science Engineering ,Beihang University , Beijing 100083, China) Abstract: This paper dealed with thewettability of SiC ceramic/ NiNb system. The results showed that the contact angle decreased with the increase of Nb content. lso, the contact angle decreased with the increasing of the temperature and pro longing of the dwelling time respectively until it reacheda stable value. The microstructure and element distribution at theweld ed area were analyzed by SEM and EDX. The results showed that thewettability was improved by adding Nb element, which induced the interfacial reaction, promotes the dissolve anddiffusion between the ceramic and the metallic materials and raises the driving force of thewettability of the system. Being a chemical wetting, the original interface ( NiNb/ SiC) was replaced by new phases. T he Ni Si compound, which ha