2,3-二巯基丁二酸对黄铜矿和辉钼矿浮选行为的影响.pdfVIP

第 36 卷第7 期 东北大学学报(自然科学版) Vo 1. 36 ,No.7 2015 年 7 月 Joumal of Nortbeastem UnÌversíty (Natural Science) Ju l. 2015 doi: 10. 3969/j. issn.1005 -3026.2015.07.023 2 ， 3- 二琉基丁二酸对黄铜矿和辉锢矿浮 选行为的影晌 李明阳，魏德洲，崔宝玉，罗 娜 (东北大学资源与土木工程学院，辽宁沈阳 110819) 摘 要:以煤油为捕收剂，研究了 2 ， 3 -二琉基丁二酸(DMSA) 对黄铜矿和辉铝矿可浑性的影响，并通 过动电位分析和量子化学计算探讨了 DMSA 与矿物之间的作用机理.浮选结果表明，DMSA 对黄铜矿抑制作 用较强，而对辉锢矿抑制很弱;获得对黄铜矿较好抑制效果时，其用量仅为硫化铀的 119 - 1113. 动电位测试 结果显示，DMSA 在黄铜矿和辉锢矿表面均有吸附，但在黄铜矿表面的吸附作用强于辉锢矿.量子化学计算 表明，DMSA 与黄铜矿发生电化学作用，而不与辉铝矿发生反应. 关键词:黄铜矿;辉铝矿;浮选分离;2 ， 3 -二琉基丁二酸;动电位;前线轨道 中圄分类号: TD 923.14 文献标志码:A 文章编号: 1005 -3026(2015)07 -1020 -05 Flotation Behavior of Chalcopyrite and Molybdenite in the Presence of 2 ,3-Disulfanylbutanedioic Acid LI Ming-yαng ， WEI De-zhou , CUI Bα0-户t ， LUO Nα， (School of Resources Civi1 Engineering , Northeastem University , Shenyang 110819 , China. Corresponding author: WEI De-zhou , professor , E-mail:dzwei@mail. neu.edu.cn) Abstract: The effect of 2 , 3-disulfanylbutanedioic acid (DMSA) on the flotability of chalcopyrite and molybdenite with kerosene as a collector was investigated. The interaction mechanism between the DMSA and minerals was explored via Zeta potential analysis and quanωm啕chemistry calculation. FIotation results showed that DMSA has strong depression effect on chalcopyrite but slightly inhibition effect on molybdenite. Optimal sep缸ation efficiency is obtained when DMSA concentrate was only 1/9 - 1/13 of sodium sulphide. According to the results of Zeta potential test , DMSA adsorbs both on chalcopyrite and molybdenite surface , but the adsorption ability of DMSA on chalcopyrite surface is much stronger than 由at 00 molybdenite. The results of