不同cu 源与zn 源对cuznal 催化剂催化合成气制乙醇 - 燃料化学学报.pdfVIP

第43卷 第7期 燃摇 料摇 化摇 学摇 学摇 报 Vol.43 No.7 2015年7月 Journal of Fuel Chemistry and Technology Jul. 2015 文章编号:0253鄄2409(2015)07鄄0852鄄05 不同Cu源与Zn源对 CuZnAl催化剂催化合成气制乙醇性能的影响 李摇 超,陈永恩,黄摇 伟,高志华 (太原理工大学 煤科学与技术教育部与山西省共建重点实验室,山西 太原摇 030024) 摘摇 要:采用完全液相法以不同的铜源和锌源为原料制备了CuZnAl催化剂,在浆态床反应器中考察了其催化合成气合成乙 醇的性能,并采用XRD、H 鄄TPR、NH 鄄TPD鄄MS及BET技术对催化剂进行表征。 结果表明,以乙酸铜替换硝酸铜,抑制了热处 2 3 理过程中Cu O 的还原,提高了催化剂的比表面积,为催化剂具有较高的乙醇选择性提供了适宜的酸中心和孔径,其总醇选择2 性达45.6%,总醇中乙醇所占比例达28.7%。 关键词:CuZnAl催化剂;乙酸铜;乙酸锌;合成气;乙醇 中图分类号:O643摇 摇 文献标识码:A Effect of the source of Cu and Zn on the ethanol synthesis from syngas over CuZnAl catalyst LI Chao,CHEN Yong鄄en,HUANG Wei,GAO Zhi鄄hua (Key Laboratory of Coal Science and Technology,Ministry of Education of China and ShanxiProvince,Taiyuan University of Technology,Taiyuan摇 030024,China) Abstract:CuZnAl catalysts were prepared using different sources of copper and zinc through complete liquid鄄 phase technology. The catalytic performancesfor the ethanol synthesisfrom syngaswere investigated in a slurry phase reactor. The catalysts were characterized by XRD,H 鄄TPR,NH 鄄TPD鄄MS and BET technology. The 2 3 results suggest that replacing copper nitrate with copper acetate would restrain the reduction of Cu O in the heat 2 treatment and raise the surface areasof the catalysts. It alsoprovides suitable acid sitesandpore sizesfor higher ethanol selectivity. The selectivity of total alcohols reaches 45. 6% and the ethanol selectivity accounts for 28.7%. Key words:CuZnAl catalyst;copper acetate;zinc acetate;syngas;et