牛粪生物炭对磷的吸附特性及其影响因素研究.pdfVIP

中国环境科学 2015 ,35(4): 1156-1163 China Environmental Science 牛粪生物炭对磷的眼附特性及其影晌因素研究 马锋锋，赵保卫工钟金魁，刁静茹，张 艺(兰州交通大学环境与市政工程学院，甘肃兰州 730070) 摘要:以牛粪生物炭为吸附剂，采用平衡吸附法研究了牛粪生物炭对磷的吸附特征.研究了 pH 值、共存离子、反应温度、投加量、热解温 度等对牛粪生物炭吸附磷的影响.结果表明，牛粪生物炭吸附磷的最佳初始pH值为7.0;共存离子的存在对生物炭吸附磷的影响有限;反应温 度升高不利于磷的吸附:当投加量为 O.lg 时，对磷的去除率较为理想;热解温度升高不利于对磷的吸附.通过对实验数据进行动力学、吸附等 温线及热力学分析，发现牛粪生物炭对磷的吸附动力学数据符合拟二级吸附动力学方程，Langmuir-Freund1ich(K=û.9705) 和 Temkin(K=û.9556)方程能很好地描述磷在牛粪生物炭上的吸附行为热力学分析结果显示 25凡45C 下的吉布斯自由能变化仙的分别为 -17.43,-15.98,-15.89kJ/mo1， 表明牛粪生物炭对磷的吸附是自发的过程. 关键词:生物炭:牛粪:吸附:磷 中图分类号: X705 文献标识码:A 文章编号: 1000-6923(2015)04-1156-08 Characteristics phosphate adsorption onto biochars der如ed from dairy manure and its inßuencing factors. MA Feng-feng, ZHAO Bao-wei*, ZHONG Jin-kui, DIAO Jing-ru, ZHANG yi (School of Environmental and Municipal Engineering,L缸曲ouJiω，tong Universi纱， L扭曲ou 730070, China). China Environmental Science, 2015 ,35(4): 1156- 1163 Abstract: Characteristics phosphate adsorption onto biochars derived 企om daÍly manure was investigated by batch adsorption experiments , and the influences of pH, coexisting anions, temperature , dosage of biochar, and pyrolysis temperature on the phosphate adsorption were studied. The results indicate that the optimal initial pH value for phosphate adsorption was 7.0 , and low temperaωre favored the adsorption of phosph创e. The coexisting anions had little effect on the adsorption and the optimal dosage of biochar for removing phosphate was O.lg.η1e adsorption kinetic was well described by Pseudo-second kinetic model , whereas adsorption isotherm results elucidated that Langmuir-Freundlich 2 2 (R =0.9705) and Temkin (R =O .9556)model provided the best fit for the equilibrium data. Furthermore, with regard to 0 thermodYnan1ic 阳ame