钛酸钡的制备及光催化性能研究.pdfVIP

第20卷 第4期 湖南理工学院学报(自然科学版) Vo1．2O NO．4 2007年 l2月 Journal ofHunan Institute ofScience and Technology(Natural Sciences) Dec．枷 7 钛酸钡的制备及光催化性能研究 刘海波 ，阎建辉2 (1．湖南民族职业学院，湖南 岳阳 414006；2．湖南理工学院 化学化工系，湖南 岳阳 414006) 摘 要：溶胶．凝胶法制备了纳米BaTiO3，用XRD、SEM分析了BaTiO3的表面形态、结晶度和粒径等，在紫外光下， 以甲基橙为被降解物对其光催化活性进行了评价．结果表明，制备得到的钙钛矿型BaTiO ，颗粒较均匀，结晶度好。其粒 径约为 52．4nm，样品有严重的团聚 在紫外光下，BaTiO3对甲基橙溶液有较高光催化活性，当甲基橙溶液初始浓度为 10mg-L一、pH=3、光催化弈l用量2．5g·L～、通空气量20L·h～、光催化反应lh后，甲基橙的光催化降解率可迭81 63％． 关键词：BaTiO3；光催化反应：甲基橙 中图分类号：O614．23 文献标识码：A 文章编号：1672．5298(2007)04．0076 04 Research on preparation and photocatalytic performance of BaTiO3 LIU Hai—bo ，YAN Jian—hui2 (1．Hunan Vocational College for Nationalities，Yueyang 414000，China； 2．Department of Chemistry and Chemical Engineering，Hunan Institute of Science and Technology,Yueyang 4 1 4006，China) Abstract：The nano—BaTiO1 were prepared by a sol—gel method．The surface morphology．crystallinity and particles diameter were analysed by XRD and SEM．Under the irradiation of HV-light the photocatalytic activity of them were evaluated according to degrade methyl orange as a probe reaction．The results show that perovskite BaTiO1 had symmetrical particles(particles diameter about 52．4nm)and well crystallinity．but severely coacervation．The BaTiO1 had high photocatalytic activity under the irradiation of HV—light，The methyl orange of photocatalytic degradation rate Was 8 1．63％ after photocatalytic reaction l h when the concentration ofmethyl orange was l0 mg L～，pH 3，the dosage ofphotocatalysts was 2．5g L～，air quantity Was 20 L·h一 Key words：BaT101： photocatalytic reaction； methyl orange BaTiO 是一种新型的功能材料，其粉体的制备方法主要有：固相煅烧法、化学共沉淀法、溶胶．凝胶法、 微乳液法、水热法[1-3]等．作为一种优良的介电材料、压电材料和铁电材料，BaTiO3广泛应用于电容器、 PTC元件、压电换能器等电子元器件的制