强碱溶液中电沉积金属锌粉技术-南华大学学报·社科版.PDF

第28卷第1期 南华大学学报(自然科学版) Vol郾28 No郾1 2014年3月 Journal of University of South China(Science and Technology) Mar郾2014 文章编号:1673-0062(2014)01-0097-05 强碱溶液中电沉积金属锌粉技术 刘摇 清,周摇 逸,张艳霞 (南华大学 污染控制与资源化技术湖南省重点实验室,湖南 衡阳421001) 摘摇 要:碱浸—电解法制备金属锌粉技术具有流程简单、环境友好、适应性强等特点. 本文通过能斯特方程计算了强碱性溶液中锌沉积的理论分解电动势,并考察碱浓度、 锌浓度、极距、电流密度、搅拌等参数对金属锌粉质量和电流密度的影响,得到最佳的 2 电解条件为:碱浓度4 mol/ L,锌浓度30 g/ L,极距3 cm,电流密度1000 A/ m ,不搅 拌.在最佳条件下电解得到的金属锌粉,全锌含量为 97. 38%,金属锌含量为 96郾79%,基本达到《锌粉的质量技术要求(GB/ T6890—2000)》的一级标准. 关键词:金属锌粉;碱溶液;电沉积;电解参数 中图分类号:O646摇 摇 摇 文献标识码:B The Technology of Electrodeposition of Metallic Zinc Powder in Alkali Solution LIU Qing,ZHOU Yi,ZHANG Yan鄄xia (The Hunan Key Laboratory of Pollution Control and Resource Reuse, University of South China,Hengyang,Hunan421001,China) Abstract:The technology ofproductionofmetalliczincpowderfromleanoresbearingzincand thewastes using alkaline leaching and electrowinning process has the advantages of simple flowshee,environmental friendly and fine adaptability.In this paper,the electrode potential of zinc electrodeposition in alkali solution had been calculated and the effect of zinc and alkali concentration,current density,polardistanceandstirringonthequality of metalliczincpowder and current efficiency had been studied.Optimum conditions of zinc electrodeposition were 2 found tobe4mol/ LNaOHconcentration,30g/ Lzincconcentration,1000A/ m currentdensi鄄 ty and3cmpolar distance.The to