化学吸收-生物还原处理烟气中氮氧化物：烟气组成的影响.doc

（该文已浙江大学学报(工学版) , 2008, 42(12), 2222-2227） Effect of flue gas composition on NOx removal by chemical absorption-microbial reduction JIANG Jin-lin1, LI Zi-ting2, ZHANG Shi-han1, WU Cheng-zhi1, LI Wei1 ( 1. Institute of Environmental Engineering, Zhejiang University, Hangzhou 31027, China； 2. Zhejiang Supcon Instrument Limited Company, Hangzhou 310053 , China ) 摘要：针对烟气中存在一定含量的O2和二氧化碳CO2，研究了模拟烟气中O2以及CO2的存在对连续运行的化学吸收－生物还原集成烟气脱硝系统的影响。结果表明： 50℃时，尽管模拟烟气中氧气从0增加到5%，吸收液的溶解氧升高0.85 mg/L，造成有效吸收液成分Fe(II)EDTA（EDTA：）浓度有所下降，但由于生物还原的作用，使得Fe(II)EDTA可以有效再生，系统一氧化氮（NO）去除效率只是从95%降低到90%，NO的去除效率仍维持在较高的水平；烟气中的CO2能缓冲吸收液的pH值，使pH维持在6.57.0，从而有利于脱硝系统的连续运行；对负荷的考察证实了氧气的增加会降低系统的生物还原负荷。 关键词：烟气脱硝；化学吸收；生物还原；O2；Fe(II)EDTA Abstract: Since O2 and CO2 were always present in the flue gas, the influence of O2 and CO2 in simulative flue gas on NO removal efficiency by chemical absorption-microbial reduction integrated approach had been demonstrated. The results indicated that the dissolved oxygen in absorption solution was up to 0.85 mg/L as O2 volume ratio from 0 to 5%, which result in decrease of the concentration of active Fe(II)EDTA(EDTA: ethylenediaminetetraacetate) at 50℃. But the NO removal efficiency just decreased from 95% to 90% because Fe(II)EDTA could be regenerated effectively in virtue of microbial reduction. CO2 in flue gas could buffer the pH value of absorption solution between 6.5 and 7.0, which was beneficial to the continuous running efficiency of the NO removal system. The examination of the treatment load of the NO removal equipment confirmed that the biological reduction loading rate would fall when O2 volume ratio of input gas increased. Keywords: flue gas denitrification; chemical absorption; microbial reduction; O2; Fe(II)EDTA 烟气脱硝技术的研究引起国内外的广泛关注。迄今为止，在国际上选择催化还原（SCR）及选择性非催化还原技术（SNCR）NOx脱除效率较低 [1-4]。为此，探索更为经济有效的脱硝新技术成为必要。 络合吸收法是世纪80年代发展起来的一种烟气脱硝方法，在美国、日本等国得到了比较深入的研究。其中，利用亚铁络合物来吸收一氧化氮的方法，已做了大量的研究Fe(II)EDTA具有吸收容量大、吸收速率快、价廉易得、在反应过程中相对稳定等优点[-12]，但是存在吸收剂容易被氧化的Fe(III)EDTA的缺点。因此，吸收剂再生的问