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Thermochimica Acta 517 (2011) 63–73 Contents lists available at ScienceDirect Thermochimica Acta j o u rn al h omepage: w w w. elsev /locate/tca Supramolecular liquid crystals in binary and ternary systems Magdi M. Naoum ∗ , Abdelgawad A. Fahmi, Mohamed A. Alaasar, Rim A. Salem Department of Chemistry, Faculty of Science, Cairo University, Giza 12613, Egypt a r t i c l e i n f o a b s t r a c t Article history: Five, new laterally methyl-substituted, pyridine-based derivatives (I8–I16) having molecular formula 4- Received 6 December 2010 C H O–C H COOC H (2-CH )–N N–C H N, with n varies between 8 and 16 carbons, were prepared n 2n+1 6 4 6 3 3 5 4 Received in revised form 1 January 2011 and investigated for their mesophase behavior by differential scanning calorimetry (DSC) and polarized Accepted 22 January 2011 light microscopy (PLM). All prepared homologues were found to be smectogenic, possessing the smectic Available online 26 February 2011 C mesophase. Binary mixtures, covering the whole concentration range, were independently prepared from corresponding isomers, one from series In and the other from series IIn, in which the methyl group Keywords: is introduced this time into position-3. All mixtures were similarly characterized and their binary-phase Supramolecular LCs diagram