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第 19 卷第 3 期 中国有色金属学报 2009 年 3 月 Vol.19 No.3 The Chinese Journal of Nonferrous Metals Mar. 2009 文章编号：1004-0609(2009)03-0589-06 精铟的化学清洗提纯 于丽敏，蒋文全，孙海峰，傅钟臻，夏 雯，刘 红，孙泽明 (北京有色金属研究总院 分析测试中心，北京 100088) 摘 要：研究精铟的化学清洗提纯过程，提出甘油碘化钾熔炼及甘油氯化铵熔炼相联合进行化学提纯的方法。研 −6 以下，并可直接得到表面光亮平整无杂色的铟电极，化学清洗 究表明：该方法可将镉、铊等杂质含量降低到 10 提纯工艺简单易操作；甘油碘化钾熔炼提纯的最佳实验条件是质量比控制在 m(KI)׃m(In) ≥0.01，m(glycerin)׃m(In) ≥0.3，搅拌时间控制在 1 h；甘油氯化铵处理时氯化铵的用量应控制在 m(NH Cl)׃m(glycerin)=0.15 。 4 关键词：精铟；化学清洗；甘油；碘化钾；氯化铵 中图分类号：TF 114.1 文献标识码：A Chemical purifying process of refined indium YU Li-min, JIANG Wen-quan, SUN Hai-feng, FU Zhong-zhen, XIA Wen, LIU Hong, SUN Ze-ming (Analysis and Measurements Research Center, General Research Institute for Non-ferrous Metals, Beijing 100088, China) Abstract: The chemical purifying process of refined indium was studied. In order to remove impurities Cd and Tl effectively, glycerin-KI and glycerin-NH Cl were used simultaneously to purify indium. The results show that through 4 this method the contents of impurities Cd and Tl in indium can be reduced to less than 10−6, thus refined indium anode with smooth and bright surface can be gained directly and easily. The best experimental conditions of glycerin-KI are m(KI)׃m(In) ≥0.01, m(glycerin)׃m(In) ≥0.3, and the stirring time should be controlled within 1 h. The ammonium chloride concentration should be controlled within m(NH4Cl)׃m(glycerin)=0.15. Key words: refined indium; chemical purifying process; glyce