高压烧结的BaTiO3陶瓷的介电性能.pdfVIP

第30卷第4期 压 电 与 声 光 VoI．3O No．4 2008年8月 PIEZOELECTECTRICS＆ AC0UST00PTICS Aug．2008 文章编号：1004—2474(2OO8)O4—0465—03 高压烧结的BaTiO3陶瓷的介电性能 肖长江 ，王春华 ，靳常青 ，王晓慧。 (1．河南工业大学 材料科学与工程学院，河南 郑州450007；2．中国科学院 物理研究所北京 100080； 3．清华大学材料科学与工程系新型陶瓷和精细工艺国家重点实验室，北京 100084) 摘 要：用两种高压法烧结得到致密的细晶BaTiO。陶瓷。由压力辅助烧结得到的陶瓷晶粒没有过分长大，晶 粒尺寸保持在纳米尺度内；用高压成型常压烧结法得到的陶瓷晶粒明显长大。当BaTiO。陶瓷的晶粒尺寸从 400 am减小到50 am时，相应的介电常数从 3 000减小到1 900。介电常数的减小可由晶粒尺寸的减小而导致四方 度的降低和非铁电低介电常数的晶界层解释。且铁电一顺电转变由一个尖锐峰变成一个宽的区域，宽的转变区域 表现出扩散相变的特征。 关键词：BaTiO。陶瓷；高压；介电性能；扩散相变 中图分类号：TB34 文献标识码：A Dielectric Properties of BaTiO3 Ceramics Sintered by High—pressure Approaches XIAO Chang-jiang ”。WANG Chun—hua ，JIN Chang-qing。，WANG Xiao-hui。 (1．Dept．of Material Science and Engineering，Henan University of Technology，Zhenzhou 450007，China； 2．Institute of Physics，Chinese Academy of Science，Beijing 100080，China；3．State Key Lab．of New Ceramics and Fine Processing，Dept．of Material Science and Engineering，Tsinghua University，Beijing 100084，China) Abstract：Dense BaTiO3 ceramics were prepared using two high-pressure approaches．The grains did not execs— sively grow sintering by the high—pressure assisted sintering，and the grains still retained in the range of nanometer size．The sintering temperature obviously decreased when the raw powders were consolidated under high pressure and then sintered at ambient pressure．With grain size reducing from 400 am to 50 am，the dielectric constant de— creased from 3 000 to 1 900。which could be explained by the tetragonality decreasing and the existence of a low—per— mittivity，nonferroelectric grain boundary layer in dense BaTiO3 ceramics．In addition，with reducing the grain size， the character of the ferr