TDA同分异构体的分离王勇.pdf

24 　6 　　　　　　　 Vol.24 No.6 2003 12 Journal of Qingdao University of Science and Technology Dec.2003 　　:1001-4 64(2003)06-0484-04 TDA 　, , , (, 266042) 　:从TDA 的同分异构体中分离得到间位TDA 难度很大,针对常用的两塔正次序分 离法存在物料 留时间长、能量消耗大、发生副反应等缺点,提出了采用带侧线采出的复 杂精馏塔分离方法,使得物料的 留时间缩短, 能耗减少约22 %。 :TDA;同分异构体;塔的总组合曲线 :TQ 021.8　　　:A Study on Separation of TDA Isomers WANG Yong, LI Yu-gang, KONG Ling-qi, ZHENG S i-qing (Research Center for Computers and Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China) Abstract:It is difficult to separate m-TDA from TDA isomers.There are some defects in the sepa- ration method using two columns, such as long residence time, huge energy expenditure and side re- actions.A new separation method using a complex column with side discharge was studied.In this method, residence time of streams became shorter and energy expenditure decreased about twenty- two percent. Key words:TDA;isomer;CGCC 　　(TDA) 、TDA (TDI),(DNT ) ,,TDA , 0.01%。TDA TDA (2,4-、2,6-) TDI。TDA TDA。 TDI, ,, 。 。TDA , [1] TDI , 。 , TDA , 。 ,TDA。 1　 TDA , , 。, TDA DNT TDA、 [1～3] 。 、TDA 。 TDA, 、 , 。 :2002-03-03 :　(19 9～), , ;　:(1962 ～), , 6 　　　　　　　　　　　　　:TDA 　　　　　　　　　　　48　5 TDA , ,2 。、 ,。