利用硫化亚铁做还原剂处理废旧干电池制取硫酸锰的研究.pdfVIP

33 1 ( 190 ) V ol. 33 No. 1( Sum. No . 190) 20 11 1 Envir onment and Ecolo gy in the T hr ee Gorges an. 20 11 段雪梅, 巢文军 ( , 2 1300 1) : ( MnSO ) 4 : : 15 mL, 70 , 08 g 3 h , 80% : ; ; : X 705 : A : 2011) Study on Producing Manganese Sulfate with Ferrous Sulfide asReductant from the Waste Zn/ Mn Battery Treatment DU AN Xuemei, CHA O Wenjun ( Environm ental Monitoring C enter Station of C han gzhou, Changzhou 213001, China) Abstract: Ex per imental principle, technolog ical process and co nditions w ere studied on pr oducing mang anese sulfate wit h ferrous sulfide as reductant for treating w ast e Zn/ Mn dry battery . T he results show ed that sulfur ic acid con centration and amount of ferrous sulfide affect the r eact ion r emarkably. It was concluded that the optimal reactio n co nditions for pr oducing mang anese sulfate w ere: sulfur ic acid of 15 mL , the ferrous sulfide of 0. 8 g , reactio n time of 3 hour s at 70 and the recovery r ate of manganese sulfat e over 80% . ey words:ferrous sulfide; dry battery ; manganese sulfate , ( 3% ) , 60 1 h, 917% , [ 9] , 983% [ 14] , , ( 750 , , , 1 h) ( 1 1) , , 945% , , 936% , [ 47] , , , [ 8] , , , 1 , 11 540 g, 20 mL H NO3 ( 1 1) , 40 mL H2 O2 , ,