镁铝水滑石的合成及其表征.pdfVIP

第 28卷 第 4期 青 海 大 学 学 报 ( 自 然 科 学 版 ) Vol28 No4 2010年 8月 Journal ofQ inghaiUniversity( Nature Science) Aug2010 , , , (, 81001 ) : 为了探讨镁铝水滑石的合成条件, 采用共沉淀法制备镁铝水滑石对比确定了最佳反应 温 和利于离子交换的 NaOH 沉淀剂在 1940和 75 晶化温 下制备 3种水滑石, 利用 XRD和 SEM 对制备的镁铝水滑石进行分析结果表明, 75 下制备出的水滑石结晶 较高, 物相纯净, 并具有典型层状结构, 为进一步研究聚合物基水滑石复合材料奠定了基础 : 水滑石; 合成; XRD; 复合材料 : TG14 : A : 100 - 899 ( 2010) 04- 0022- 05 Synthesis and characterization ofMg/Al layered double hydroxide GAO L,i ZHANG Xingru, UAN Guoping, CHEN Liwei (Q inghaiUniversity, X in ing 81001 , China) Abstract: In order to confirm the synthesis cond ition of layered double hydroxide compound ( LDH ), theMg/A l layered double hydroxidew as synthesized by using co- precipitation. The best reaction temperature w as found and the best precip itating agent NaOH w as confirm ed. F irst three k inds of LDH w ere synthesized at 19, 40 and 75 , and then the structuresw ere characterizedw ith XRD and SEM. The results show ed the sample w ith 75 reaction temperature w as pure, and had the best crystallin ity and typical layered structure. The successfu l preparation ofLDH lays a founda tion for the polymer/LDH composites. Key words: LDH; synthesis; XRD; composites ( Layered double hydroxide compounds, LDH ), , , [ 1- 3] , , [ 4- ] LDH , Mg( OH ) , 2 MO M g A l ( OH ) CO 4H O 2 1 3 2 , , , 1 11 A l( NO ) 9H OMg( NO ) H ONaOHNa CO , 3 3 2 3 2 2 2 3 : 2010- 05- 05 : 青海大学中青年科研基金项目