六水氯化钙相变材料过冷性质的研究 徐云龙.pdfVIP

218 　　 / 2006 　 1　 Preliminary Supercooling Research on Calcium Chloride Hexahydrate as Phase Change Material , 　( , 200237) XU Yun- ong IU Dong(Key aboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237, China) :CaCl 6H O (PCM), 2 2 。 , , CaCl 6H O , 2 2 。, CaCl 6H O 2 2 。 , SrCl 6H O CaCl 6H O , CaCl 6H O 2 2 2 2 2 2 2℃ 0℃, 。 :;;; :O78　　:A 　　:100-1 4381(2006)Supp-l 021-8 04 Abstract:Calcium chloride hexahydrate has broad application prospects in thermal energy storage fields as a normal and low temperature phase change materials(PCMs). However,further applications of it are inhibited by its serious supercooling. In order to solve this problem, calcium chloride hexahy- drate adulterated with various substances were prepared with‘solution method’, based on the nuclea- ting mechanism and characterized by thermal gravitation analysis(TGA ). In addition, The effects of adding methods of various nucleators as well as technical parameters on the supercooling properties of calcium chloride hexahydrate were researched under the condition of room temperature cooling and ‘open system’. It is demonstrated in the experimental results that strontium chloride hexahydrate and borax are satisfactory nucleators of calcium chloride hexahydrate, and are ab