石蜡 改性硅藻土复合相变储能材料的制备及性能研究 孙跃枝.pdfVIP

Vol.38 No.4 　　　　　 38 4 ·46 · NEW CH EM ICAL MATERIA LS 2010 4 / 1, 2 1 ＊ 1 1 孙跃枝 　席国喜 　杨文洁 　邢新艳 (1.河南师范大学化学与环境科学学院河南省环境污染控制重点 验室,新乡453007; 2.焦作师范高等专科学校生化系, 焦作 454000) 　　以石蜡为相变储能材料, 改性硅藻土为载体, 无水乙醇为溶剂采用溶液插层法制备了石蜡/改性硅藻土复合 相变储能材料, 利用综合热分析仪 (T G-DSC)测定了复合材料的相变温度、相变潜热及复合材料的热稳定性, 通过扫描电 镜(SEM)、FT-IR 分别对复合材料的微观结构及兼容性进行了表征, 结果表明:复合相变储能材料中石蜡的适宜含量为 65%, 此时相变温度为53.7℃, 相变潜热为147.93J/g, 复合材料具有良好的热稳定性和兼容性。 　复合相变材料,石蜡, 改性硅藻土 Preparation and study on paraff in/modified kieselguhr composite phase change material 1,2 1 1 1 Su Yuezhi 　Xi Guoxi 　Ya g We jie 　Xi g Xi ya (1.Key Laboratory for E viro me tal Pollutio Co trol,College of Chemistry a d E viro me tal Scie ce of He a Normal U iversity,Xi xia g 453007; 2.Jiaozuo Normal College, Jiaozuo 454000) Abstract 　Paraffi as phase cha ge material, modified kieselghur as carrier, etha ol as solve t, composite phase cha ge material w as prepared by solutio i tercalated reactio .Phase cha ge temperature a d late t heat of composite PCM a d the thermal stability were characterized usi g sy thesized thermal a alyzer.The chemical compatibility a d mi- crostructure of composite PCM w ere characterized usi g SEM a d FT-IR.The results show ed that the paraffi s maximum of PCM w as 65%, phase cha ge temperature was 53.7 ℃,phase cha ge late t heat w as 147.93 J/g ;the thermal stability a d chemical compatibility of PCM w ere better. Key words　composite phase material, paraffi , modified kieselguhr 　　(PCM), 、 (), ,