煤粉物化特性对燃烧后灰颗粒物的影响 - 燃料化学学报.pdf

第39卷 第6期 燃摇 料摇 化摇 学摇 学摇 报 Vol.39 No.6 2011年6月 Journal of Fuel Chemistry and Technology Jun. 2011 文章编号:0253鄄2409(2011)06鄄0419鄄06 煤粉物化特性对燃烧后灰颗粒物的影响 吕建燚,李晶欣 (华北电力大学 环境科学与工程学院,河北 保定摇 071003) 摘摇 要:以三种煤粉在沉降炉中做燃烧实验,用Andersen粒子撞击器分离并捕集燃烧后的灰颗粒物,借助于压汞仪、扫描电 镜及能谱、ICP鄄AES等对煤粉及分级颗粒物进行检测,研究煤粉物化特性对灰颗粒物的粒径分布、形貌、组成、痕量元素的富集 等特性的影响。 结果表明,煤粉孔结构、组分的赋存方式及含量等影响其破碎行为及组分迁移、转化的过程,从而形成形态、 大小不同的颗粒物,呈现出不同的粒径分布特性,同时影响元素的蒸发和凝结及其在分级颗粒物中的再分配过程。 关键词:煤粉燃烧;物化特性;颗粒物;痕量元素 中图分类号:TK16;X513摇 摇 文献标识码:A Influence of coal physicochemical properties on ash particulate matter after coal combustion L譈 Jian鄄yi,LI Jing鄄xin (School of Environmental Science and Engineering,North China Electrical Power University,Baoding摇 071003,China) Abstract: Three coals were combusted in a drop tube furnace. An Andersen particle sizing impactor was employed to separate and collect the ash particulate matter (PM) after coal combustion. Mercury injection apparatus,SEM鄄EDX,ICP鄄AES were taken to detect the tested coals and graded ash PM. The effect of coal physicochemical properties on ash particle size distribution (PSD),appearance,constituents and enrichment of trace elementsof PM wasexamined. Theresults show that thepore structure of coals,occurrence characteristics and concentration of constituents influence the behavior of ash fragmentation and the transition procedure of constituents, forming different morphological and inequable PM, and leading to the different PSD. Simultaneously,they will influence the vaporization and coagulation of elements as well as the redistribution in the graded PM. Key words:pulverized coal combustion;physical鄄chemistry features;particulate matter;trace elements