深入探析低浓度铜阳极泥加压浸出液中银硒碲的分离.docVIP

低浓度铜阳极泥加压浸出液中的铜粉Ag、SeTe的试验研究，结果表明：控制置换反应温度分别为≤45℃（低温）、≤75℃（中温）、≥95℃（高温）时，可以分别得到以银为主的银渣、以硒为主的硒渣和含银硒很低的碲渣，当铜阳极泥加压浸出液的碲浓度很低时，先采用铜粉Ag、Seeparation of Silver, Selenium and Tellurium in Low Concentrations of Copper Anode Slime Pressure Leaching Solution ZhONG Qing-Shen1,2,HE Xiu-Zhen2,LIU Yu-Qiang1,2,MA Yu-Tian1 （1.Jin Chuan Precious Metalls Research Centre, Jin Chuan Group.Ltd,Jin Chang Gansu Province 737100,China,2.School of Metallurgical Engineering,Xi,an University of Architecture and Technology, Xi,an Shanxi Province 710055,） Abstract: for low concentration from copper anode slime pressure leaching liquid separation of silver, selenium and tellurium, respectively for the copper powder replacement of thermodynamics analysis, single factor affecting the displacement test, as well as the silver selenium tellurium step-by-step substitution test and copper powder replacement Ag, Se step by step, the crystallization mother liquor of copper powder cementation Te experimental study, the results show that the control displacement reaction temperature respectively for 45 ℃ or less (low temperature), 75 ℃ or less (temperature), and 95 ℃ or higher (high temperature), can be given priority to with silver silver, respectively is given priority to with selenium selenium residue and low silver selenium tellurium slag, when copper anode mud pressure leaching liquid of tellurium concentration is low, the first adopts copper powder, replacement Ag, Se, recrystallization of copper, copper removal mother liquor with copper powder replacement, tellurium replacement rate above 99%, tellurium slag replacement tellurium quality score as high as 36 ~ 43%, facilitate subsequent tellurium extracting and refining. Keywords: low concentration of copper anode slime pressure leaching liquid; Copper powder replacement; Tellurium; Selenium; Silver; Replacement rate 0引言 硒、碲是重要的稀散金属，在现代高新技术产业中具广泛的用途。随着高新技术的迅猛发展，其应用领域和规模扩大需求日益增加。 工业提取硒、碲的原料，主要有铜电解阳极泥或铅电解阳极泥等。目前工业铜阳极泥的工艺有火法工艺和湿法工艺等，用的活性铜粉置换出Ag、Se和Te综合回收银、