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Dyes and Pigments 96 (2013) 509e515 Contents lists available at SciVerse ScienceDirect Dyes and Pigments journal homepage: www.else /locate/dyepig A new selective pyrazoline-based fluorescent chemosensor for Cu2þ in aqueous solution Shengli Hu a, *, Shushu Zhang a, Yang Hu a, Qing Tao a, Anxin Wu b, ** a Hubei Key Laboratory of Pollutant Analysis Reuse Technology, Department of Chemical and Environmental Engineering, Hubei Normal University, Huangshi 435002, PR China b Key Laboratory of Pesticide Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, PR China a r t i c l e i n f o a b s t r a c t Article history: A new pyrazoline derivate was designed and synthesized. The structure of the pyrazoline was confirmed Received 27 July 2012 by single crystal X-ray diffraction and its photophysical properties were studied by absorption and Received in revised form fluorescence spectra. This compound can be used to determine Cu2þ ion with high selectivity and 25 September 2012 sensitivity among a series of cations in aqueous tetrahydrofuran. This sensor forms a 1:1 complex with Accepted 27 September 2012 2þ Available online 6 October 2012 Cu and displays fluorescent quenching. 2012 Elsevier Ltd. All rights reserved. Keywords: Pyrazoline Fluorescent sensor Copper ion detection Sele