LiFePO4充放电过程界面性能研究 Investigation on the interface properties of LiFePO4 during charge and discharge process.pdfVIP
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LiFePO4充放电过程界面性能研究 Investigation on the interface properties of LiFePO4 during charge and discharge process
电池工业
LiFeP04充傲电过程界面性能研究
白咏梅1,陈 晗2,韩绍昌r
(1.湖南大学材料科学与工程学院,湖南长沙410082;2.湖南工业大学冶金学院,湖南株洲412000)
了LiFePO。的脱/嵌锂过程中的等效电路,对LiFePO。不同充放电时期试样进行电化学阻抗测试,计
算出了交换电流厶和锂离子扩散DL+。并讨论随充放电过程的进行/o和DⅡ+的变化规律。
关键词:正极材料;LiFeP04;界面
中图分类号:TM912.9文献标志码:A文章编号:1008—7923(2010)02—0084一05
ontheinterface of
LiFeP04
Investigation properties
- ● o ’● ’
1
ancI
duringchargedischargeProcess
BAI han2,HAN
Yong-meil,CHENShao-chan91+
and
Science
口.coffegeofMaterials Engineering,HunanUniversity,Changsha,Hunan410082,China;
2.College Universityof 412000,China)
ofMetallurgy,HunanTechnology,Zhuzhou。Hunan
Abstract:Thediffractionandelectrochemical wereusedto thestructural
X-ray impedancespectrum study
andinterfacebehaviors and in XRDtest
LiFePO+Theresults
changes duringchargedischargeprocesses
showedthatthe and wasina coexistenceandconversionstatebetween
chargedischargeprocess two-phase
circuitofthe intercalationanddisintercalationwasdetermined.The
LiFeP04
LiFePOA9ePO÷Equivalentduring
lithium-iondiffusion calculatedandelectrochemical
exchangecurrent㈣and coefficient(Dr.)were impedance
The
wastestedatdifferentand variationlaws the and
spectrum chargedischargestage duringcha
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