MPc-PtC复合催化剂的甲醇氧化催化活性研究 Research on catalytic activity of MPc-PtC complex catalysts to methanol electro-oxidation.pdfVIP
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MPc-PtC复合催化剂的甲醇氧化催化活性研究 Research on catalytic activity of MPc-PtC complex catalysts to methanol electro-oxidation
电池工业
MPc—Pt/C复合催化剂的甲醇氧化催化活性研究
邬静杰,潘 牧,马文涛,唐浩林,宛朝辉
(武汉理工大学材料复合新技术国家重点实验室,湖北省燃料电池重点实验室,湖北武汉,430070)
TEM图显示,Pt在复合催化剂中分散性良好,没有发生大的团聚。运用循环伏安法系统评价了这几
种复合催化剂的甲醇氧化参数,甲醇氧化峰电流(D与中间产物氧化峰电流(厶)的比值∥厶以及甲
FePc—Pt/C,即促进甲醇氧化的催化活性随金属酞菁中心金属离子3d轨道电子数增加而递增。
好。
关键词:直接甲醇燃料电池;甲醇催化氧化;金属酞菁;复合催化剂
中图分类号:TM911.14文献标志码:A文章编号:1008—7923(2008)03一0180—04
Researchon ofMPc—Pt/C catalysts
catalyticactiVity complex
tomethanolelectro一0xidation
Zhao—hui
WU Mu,MAWen—tao,TANGHao—lin,WAN
Jing_jie,PAN
形“矗帆HⅡ6ei铀9D7D,仍i删
Abstract:DifferentMPc—Pt/C toleranttomethan01
complexcatalysts (withM:Fe,Co,Ni,andCu)were
an method.PtdistributedwellintheMPc—Pt/C
synthesized complexcatalysts,and
by impregnation
electrooxidation
didn cun·entratioofmethanolandintemediate
7tasseⅡlbletogether.Thepeak pI.0ducts
andmethanoleIectrooxidationculTent werestudied.The of
(厶ⅡD peak density(U catalyticactiVity
in of
methanolelectrooxidationisincreasedsequence
with ofcenteredmetalionsincreased.Thevalueof forMPc—Pt,C
theelectronson3d—orbit J/,fJ complex
wenttostabilizationmer40scansof ofstabilizationwasobsen,ed
catalvsts cycIicvoltage.Enhancement
fbrCuPc—Pt/C.
words:DMFC;methanolelectrooxidation;metal catalysts
Key phthalocyanine;compIex
(6.1
直接甲醇燃料电池(DMFC)
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