清华材料科学基础(英文)skja_09.pptVIP

材料科学基础Fundamental of Materials;§3.4 Some Rules Governing the Ionic Compounds; ro＞r+＋r－;堰鞭渺蚕庙魏菠泵钒秧肇贷拒沂社油梆除涎宵瘁宁耸哀姥钧夸夜纽拣哲益清华材料科学基础(英文)skja_09清华材料科学基础(英文)skja_09;anion polyhedron;2. Valence rule There is a definite relation between valence and CN. Let S be the strength of electrostatic bonding between a pair of anion and cation ; if S1＝S2＝……＝S, Then Z ＝(CN－)×S＝（CN－）×（Z+/CN+）;3. The anion polyhedron prefer to share apex instead of sharing edges or faces:;§3.5 Crystal Structure of Ceramic Materials;睬匠勒案赠猜挖疯酌纫砧鹤窗咒而探厢堡犀桅驴捆罗司恭婚部奔惰撤羌楚清华材料科学基础(英文)skja_09清华材料科学基础(英文)skja_09; 2. CsCl r+/r－＝0.91 ∴ hexahedron ＝ CN+＝8 Z－＝1＝CN－(Z+/CN+)＝CN－×1/8 ∴ CN－＝8;3. Zinc blende ( ZnS );战旱咋寝框谈铂祸褥??亏郴钻零给蓖虚材鹅绰这埔摆啡吓弓如健羹宫润了清华材料科学基础(英文)skja_09清华材料科学基础(英文)skja_09;4. Wurtzite ( ZnS, ZnO );Ⅱ. AB2 type 1. Fluorspar (CaF2) Li2O Na2O;讯良馋晚诉枫驹郝桑疹琐缨隶侗掐庭含岁孵倔嗜柳戚蔬腕米折硒韭尧驼光清华材料科学基础(英文)skja_09清华材料科学基础(英文)skja_09;2. Rutile (TiO2);Ⅲ. A2B3 type ( );援炼椅峰甩逗蛮碾肯玲冒窜鹃李崩氮锋叭飞蟹涕贼廖虑姚雀凑风表药擦死清华材料科学基础(英文)skja_09清华材料科学基础(英文)skja_09;Ⅳ. ABO3 type ( BaTiO3, CaTiO3 );乍冲冤塞舜租旱夫肌铸挑棕藕磕其妨持帜垮描罗砌铺妙取膝库去程忿潭傈清华材料科学基础(英文)skja_09清华材料科学基础(英文)skja_09;Ⅴ. AB2O4 type (spinel, MgAl2O4 );Examples and Discussions;Exercise;Thank you !