硅烷处理对富锌涂层行为的影响.pdf

第 17 卷 第 4 期 腐蚀科学与防护技术 Vol 17 No4 2005 年 7 月 　　　　 　　　　 J ul 2005 CORROSION SCIENCE AND PROTECTION TECHNOLOGY 硅烷处理对富锌涂层行为的影响 谢德明 , 冯　海, 马晓春 浙江工业大学 ,杭州 310032 ( ) ( 摘要 :采用测量涂层的腐蚀电位和电化学阻抗谱 EIS 等方法研究了硅烷偶联剂处理 钢铁表面的硅烷偶联剂预处 ) 理和富锌漆中掺入硅烷偶联剂 对富锌涂层在 35mass %NaCl 溶液中腐蚀行为的影响. 结果表明 ,两种硅烷处理方 式均明显延长了富锌涂层的阴极保护期. 钢铁表面硅烷处理减弱了无机富锌涂层的阴极保护作用. 关键词 :富锌漆 ;硅烷 ; 电化学阻抗谱; 阴极保护;屏蔽作用 中图分类号: TG172. 5 ; TG174. 461 　　文献标识码 :A 　　文章编号 :(2005) INFL UENCE OF SILANE MODIFICATION ON PERFORMANCE OF ZINC - RICH COATINGS XIE Deming ,FEN G Hai ,MA Xiaochun Zhejian g U niversity of Technology , Hangz hou 310032 ABSTRACT :The influence of a pretreatment with silan coupling agent of the steel substrate and addi tion of silane coupling agent to zincrichpaints on corrosion protectiveness of zincrich paints ( ZRPs) on steels was studied. Corrosion potential and electrochemical impedance spectroscop y ( EIS) measure ments were used to assess the corrosion prevention performance of the modified coatings. Furthermore , the impedance module at low frequency of coating samples were derived to assess the coating deteriora tion with time. The results showed that the modification with silane can effectively enhance the lifetime for cathodic protection period of ZRP coatings. KEY WORDS :zincrich paints ;silane coupling agent ;electrochemical impedance spectroscop y ;cathodic pr