Au纳米颗粒BFOZnO复合结构的光电化学性质的提高.pdfVIP

Applied Physics 应用物理, 2016, 6(11), 227-238 Published Online November 2016 in Hans. /journal/app /10.12677/app.2016.611029 The Enhancement of Au Nanoparticles/ BFO/ZnO Composite Structure at Photoelectrochemical Properties Shoulin Gu, Xingbo Wu, Kai Liu College of Physics, Optoelectronics and Energy, Soochow University, Suzhou Jiangsu th th th Received: Oct. 20 , 2016; accepted: Nov. 14 , 2016; published: Nov. 18 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Open Access Abstract Polycrystalline BiFeO3 (BFO) film was synthesized on the ITO conductive glass by magnetron sput- tering technique, and the appropriate amount of gold nanoparticle (Au Nps) was successfully loaded to improve the photocurrent of the sample. The surface plasma resonance (LSPR) effect of gold nanoparticles, and the formation of the Schottky barrier of metal/semiconductor interface are bene- ficial to accelerate the separation of electronic-hole. The BFO/10 nm ZnO films show denser and smoother surface and higher degree crystallization, which is beneficial to reduce the leakage current density and achieve larger double-remant-polarization value. The generation of depolarization field by polaring BFO film also promotes the separation of the electronic-hole, and prevents the rapid re- combination of photogenic charge carrier, which can obtain better photoelectrochemical properties. Keywords Au Nanoparticles, Thin BFO Films, ZnO Buffer Layer, Photoelectrochemical Properties Au纳米颗粒/BFO/ZnO复合结构的 光电化学性质的提高 古寿林，吴星波，刘 凯 苏州大学物理与光电能源学部，江苏 苏州