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化工装置腐蚀类型简介(Brief introduction of corrosion types of chemical devices)
Increased sensitivity of crevice corrosion. However, some oxygen anion increase will reduce the amount of crevice corrosion
Stress corrosion
The material in corrosive medium and in particular the static tensile stress (including external load, thermal stress, cold working and heat processing, welding residual stress caused by the cracks, and wedge rust stress), lower than the ultimate strength of brittle cracking phenomenon, known as stress corrosion cracking
Stress corrosion cracking is first formed small pits in the sensitive parts of metal corrosion, produce slender cracks, and crack propagation can occur very quickly, serious damage in a short period of time. The stress corrosion cracking in the petroleum and chemical corrosion type in the highest proportion, up to 50%? Stress corrosion has two basic conditions: one is the material with certain stress corrosion cracking of medium; two is the existence of sufficiently high tensile stress. Lead to stress corrosion cracking stress from work stress, can also be generated from the residual stress in the process of manufacturing. According to statistics, the stress corrosion cracking accident, caused by the residual stress accounted for more than 80%, less than the working stress caused by 20%.
The stress corrosion process can be divided into three stages. The first stage is the incubation period, in this period, because of the corrosion process of localization and stress results of the crack nucleation; the second stage is the corrosion crack development period, when the crack is generated, tensile stress crack interaction in the corrosive medium and the metal, in the third stage, due to expansion; local concentration of tensile stress, crack growth leading to sharp parts failure. ? in the event of stress corrosion, uniform corrosion does not occur obvious, even corrosion products rarely, sometimes the naked eye is difficult to find, therefore, str
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