高温养护对复合胶凝材料水化程度及微观形貌的影响-中南大学学报.PDF

第 41 卷第 6 期 中南大学学报( 自然科学版) Vol.41 No.6 2010 年 12 月 Journal of Central South University (Science and Technology) Dec. 2010 高温养护对复合胶凝材料水化程度及微观形貌的影响 李响，阎培渝 (清华大学 土木工程系，北京，100084) 摘 要：采取对化学结合水含量和粉煤灰反应程度的测定、形貌观察和能谱测试等手段对高温养护制度下复合胶 凝材料水化程度及硬化浆体微观形貌进行研究。研究结果表明：高温养护的热激发作用增强了粉煤灰的火山灰活 性，显著提高了早龄期体系的水化程度，而且能使粉煤灰颗粒表面产生更多水化产物，促使浆体结构更加致密； 但高温养护对 C-S-H 凝胶钙硅质量比(钙硅比) 的影响不显著，而且对后期浆体水化程度的提高以及微观结构的改 善无较大贡献。 关键词：高温养护；水化程度；微观形貌；粉煤灰；钙硅比 中图分类号：TU528 文献标志码：A 文章编号：1672−7207(2010)06−2321−06 Effect of high temperature curing on hydration degree and micro-morphology of complex binders LI Xiang, YAN Pei-yu (Department of Civil Engineering, Tsinghua University, Beijing 100084, China) Abstract: The hydration degree and microstructure of complex binders during high temperature curing were studied by determining the non-evaporable water content and the reaction degree of fly ash, observing the micro-morphology and testing spectrum. The results show that heat activation obviously enhances the pozzolanic reaction of fly ash, which elevates the early hydration degree of complex binders remarkably. More hydration products are generated on the surface of fly ash particles, which makes the microstructure of pastes more denser than that cured at room temperature. However, high temperature curing has insignificant influence on the mass ration of CaO to SiO2 of C-S-H gel in pastes and contributes little to the improvement of the later hydration degree and microstructure of complex binders. Key words: high temperature curing; hydration degree; micro-morphology; fly ash; mass ratio