核壳型导电聚苯胺符合材料的制备及性能研究.pdfVIP

Material Sciences 材料科学, 2016, 6(1), 46-52 Published Online January 2016 in Hans. /journal/ms /10.12677/ms.2016.61006 Preparation and Properties of Conducting Polyaniline Core-Shell Composite * * Li Gao , Tingxi Li , Yongqin Han, Hui Song, Chengxiang Zhang, Haibo Su, Yanmin Wang, Qing Wang College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao Shandong th nd th Received: Jan. 7 , 2016; accepted: Jan. 22 , 2016; published: Jan. 27 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract The purpose of the work is to fabricate successfully PANI via preparing core-shell structure compo- site materials through in situ polymerization. The morphology, structure crystallinity, and thermal stability of synthesized composite were investigated by Fourier Transform Infrared (FTIR), X-ray Diffraction (XRD), Thermal Gravimetric Analysis (TGA), Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). Results of the experiment indicated that core-shell structure material is successfully synthesized via in situ polymerization, and compared to signal kind material, comprehensive performance of composite is greatly improved. Electron transport properties of fluorene and thermal stability of PANI are successfully combined together. Keywords Conducting Polyaniline, Composite, Core-Shell Material, Fluorene, Electrical Properties 核壳型导电聚苯胺复合材料的制备与性能研究 * * 高 丽 ，李廷希 ，韩永芹，宋 慧，张成祥，苏海波，王延敏，王 清 山东科技大学材料科学与工程学院，山东 青岛 收稿日期：2016年1月7 日；录用日期：2016年1月22 日；发布日期：2016年1月27 日 *通讯作者