正交优化制备乳化柴油的研究.pdf

29 5 第 卷第 期 煤 炭 技 术 Vol.29,No.05 2010 5 年 期 Coal Technology May,2010 正交优化制备乳化柴油的研究 , , , 王永利 王立华 张明媚 吴 雷 （河北北方学院理学院，河北张家口075000） : 摘 要本文通过正交优化设计法探讨了乳化柴油体系中，HLB 值、乳化剂用量、助乳化剂用量（正丁醇）、乳化温度 4 种因素对乳化柴油稳定性的影响,并对乳化柴油的制备工艺进行了详细的研究.研究表明，以Span80、CTAB 进行 复配作为乳化剂,当HLB 值为8.8,乳化剂用量6.0% ，助乳化剂正丁醇与乳化剂的质量比约为1.0：2.7 ，乳化时间 30min，可以得到掺水量为14.0%的乳化柴油，该乳化柴油外观澄清透明，常温放置60d 外观无变化，稳定性较高。 : 关键词正交优化设计法；乳化柴油；乳化条件；应用 中图分类号:O174 文献标识码:A 文章编号:1008-8725 （2010）05-0224-03 Optimized by Orthogonal Design of Preparation of Emulsified Diesel Oil WANG Yong-li ，WANG li-hua ，ZHANG Ming-mei ，WU Lei （College of Science, Hebei North University, Zhangjiakou 075000,China） Abstract:Optimized by orthogonal design method to find a better preparation of emulsified diesel fuel technology ，in the system of emulsified diesel oil, HLB values, amount of emulsifier, to help emulsifier (n-butanol) , emulsifying temperature of four kinds of factors on the stability of emulsified diesel oil. The result indicate that, choosing the mixture of Span80 and CTAB as the emulsifying agent, when the HLB value is 8.8 ,the emulsifier at the percent of 6.0% and the mass ratio of the help emulsifier (n-butanol) to the emulsifier is 1.0:2.7, it prepares the emul－ sified diesel fuel with a water proportion of 14% after emulsifying in 30min. The emulsified diesel fuel appearances clarified and transparent. It can hold over 60d at the normal temperature with high stability. Key words:orthogonal design;emulsified oil;