硅藻土预涂动态膜对海水中有机物的截留及.PDF

第 11卷　 第7 期 环 境 工 程 学 报 Vol. 11,No.7 2 0 1 7 年 7 月 Chinese Journal of Environmental Engineering July 2 0 1 7 硅藻土预涂动态膜对海水中有机物的截留及 膜污染特性 王文华,赵瑾,姜天翔,张晓青,王静,张雨山∗ 国家海洋局天津海水淡化与综合利用研究所,天津 300192 摘　 要　 膜有机污染问题严重制约超滤在海水淡化预处理领域的推广应用。 通过硅藻土预涂覆强化超滤膜对海水中有机 物的截留,利用三维荧光光谱考察了硅藻土预涂动态膜对海水中典型有机污染物的净化作用,并对比分析了直接超滤和硅 藻土预涂动态膜过滤海水过程中膜通量变化及污染特性。 结果表明:硅藻土预涂动态膜对海水中DOC 和 UV 的去除率 254 分别为65.25%和92.68% ,较直接超滤分别提高了26.26%和31.10%。 通过硅藻土预涂覆能够强化超滤膜对海水中蛋白 质类有机物的截留,硅藻土预涂覆后超滤膜纯水通量略有降低。 硅藻土在超滤膜表面形成的滤饼层结构避免了膜与有机 污染物直接接触,在海水过滤过程中预涂动态膜的膜通量均高于直接超滤。 硅藻土预涂动态膜更易清洗,膜通量更易恢 复,能够有效减缓超滤膜的不可逆污染。 关键词　 超滤;海水;硅藻土预涂动态膜;有机物;膜污染 中图分类号　 X55　　 文献标识码　 A　　 文章编号　 1673-9108(2017)07-3936-07　　 DOI:10.12030/ j.cjee.201605048 Organic matter retention from seawater by dynamic membrane precoated with diatomite and its membrane fouling characterization WANG Wenhua,ZHAO Jin,JIANG Tianxiang,ZHANG Xiaoqing,WANG Jing,ZHANG Yushan∗ Tianjin Institute of Seawater Desalination and Multipurpose Utilization,State Oceanic Administration,Tianjin 300192,China Abstract　 The application of ultrafiltration (UF) in seawater desalination pretreatment is considerably con- strained by organic matter fouling the membrane. In this study,dynamic membranes pre-coated with diatomite were used to enhance organic matter rejection in seawater by UF membranes. Removal of typical organic contami- nants in seawater using diatomite dynamic membranes was investigated via excitation-emission matrix spectrosco- py. The variation of membrane flux and the characterization of membrane fouling during seawater filtration were compared for direct UF and diatomite dynamic membrane filtration. The results showed that the removal of DOC and UV via the diatomite dynamic membrane were respectively 26.26% and 31.10% higher than via direct 254 UF. U