1 Solubility Parameters — An Introduction（1介绍溶解度参数）.pdf

1 Solubility Parameters — An Introduction CONTENTS Abstract Introduction Hildebrand Parameters and Basic Polymer Solution Thermodynamics Hansen Solubility Parameters Methods and Problems in the Determination of Partial Solubility Parameters Calculation of the Dispersion Solubility Parameter, δD Calculation of the Polar Solubility Parameter, δP Calculation of the Hydrogen Bonding Solubility Parameter, δH Supplementary Calculations and Procedures Temperature Dependence Some Special Effects Temperature Changes Effects of Solvent Molecular Size Computer Programs Hansen Solubility Parameters for Water Conclusion References ABSTRACT Solubility parameters have found their greatest use in the coatings industry to aid in the selection of solvents. They are used in other industries, however, to predict compatibility of polymers, chemical resistance, and permeation rates and even to characterize the surfaces of pigments, fibers, and fillers. Liquids with similar solubility parameters will be miscible, and polymers will dissolve in solvents whose solubility parameters are not too different from their own. The basic principle has been “like dissolves like.” More recently, this has been modified to “like seeks like,” since many surface characterizations have also been made and surfaces do not (usually) dissolve. Solubility parameters help put numbers into this simple qualitative idea. This chapter describes the tools commonly used in Hansen solubility param- eter (HSP) studies. These include liquids used as energy probes and computer programs to process data. The goal is to arrive at the HSP for interesting materials either by calculation or, if necessary, by experiment and preferably with agreement between the two. INTRODUCTION The solubility parameter has been used for many years to select solvents