30 Years of Membrane Technology for Gas （30年的气体膜技术）.pdf

1999 A publication of CHEMICAL ENGINEERING TRANSA CTIONS CHEMICAL ENGINEERING TRANSA CTIONS The Italian Association VOL. 32, 2013 of Chemical Engineering Online at: www.aidic.it/cet Chief Editors: Sauro Pierucci, Jiří J. Klemeš Copyright © 2013, AIDIC Servizi S.r.l., ISBN 978-88-95608-23-5; ISSN 1974-9791 30 Years of Membrane Technology for Gas Separation Paola Bernardo, Gabriele Clarizia* Istituto di Ricerca per la Tecnologia delle Membrane, ITM-CNR, Via P. Bucci, cubo 17/C, 87030 Arcavacata di Rende, CS, Italy g.clarizia@r.it Membrane technology applied to the separation of gaseous mixtures competes with conventional unit operations (e.g., distillation, absorption, adsorption) on the basis of overall economics, safety, environmental and technical aspects. Since the first industrial installations for hydrogen separation in the early eighties, significant improvements in membrane quality have been achieved in air separation as well as in CO2 separation. However, beside the improvement in the materials as well as in membrane module design, an important point is represented by a correct engineering of these separation processes. The recovery of high value co-products from different industrial streams (e.g. organic vapours from off-gas streams, helium from natur