岩浆侵入对淮北花沟西煤中稀土元素分布的影响.PDF

2013 年 12 月，第 19 卷，第 4 期，671-676页 高 　校　地　质　学　报 December 2013，Vol. 19，No.4， p. 671-676 Geological Journal of China Universities 岩浆侵入对淮北花沟西煤中稀土元素分布的影响 刘胜军，刘文中 安徽理工大学 地球与环境学院，淮南 232001 摘要：采用 ICP-MS，XRF 等分析测试手段，对花沟西勘查区 24 件煤样和 8 件岩浆岩样品中稀土元素 (REE) 的含量进行测 定与分析，并通过对 8 号煤层和 10 号煤层中稀土元素丰度的研究，探讨了淮北花沟西勘查区煤中稀土元素的含量特征和 岩浆侵入对煤中稀土元素分布的影响。研究表明：花沟西勘查区煤中 ΣREE 平均值为 92.09×10-6 ，LREE/HREE 平均值为 6.54~8.53；岩浆侵入致使煤中稀土元素含量增加，使煤中稀土元素发生了二次迁移与富集，且岩浆组分对煤中稀土元素的 迁移富集具有一定程度的影响 关键词 ：煤；岩浆侵入；稀土元素；淮北 中图分类号：P595；P618.11　　　　　　　文献标识码：A　　　　　　文章编号：1006-7493（2013）04-0671-06 Influence of Magmatic Intrusion on the Distrbution of REE in Coals at Western Huagou, Huaibei LIU Shengjun, LIU Wenzhong School of Earth and Environment, Anhui University of Science and Technology, Huainan 232001, China Abstract: In order to investigate the abundance and distribution pattern of rare earth elements (REE) in coals at Western Huagou exploration area when coal seams were intruded by magma, ICP-MS, XRF were used to analyze in 24 coal samples and 8 magmatic rock samples. The REE’s data in the No.8 and No.10 coal-beds were compared in order to find the features of REE in coals which altered. Main conclusions are as followlng: (1) The average content of REE in coals at Western Huagou exploration area is 92.09×10-6. The value of LRRR /HREE is between 6.54 and 8.53. (2) The abundance of REE in coals was changed caused by the igneous invasion, and the intrusion lead to a second migration and enrichment of the REE. And this process will be influenced by the components of magma. Key words: coal; igneous intrusion; REE; Huaibei First author: LIU Shengjun, Master Degree Candidate; E-mail: lsj_ljz@126.com 　　两淮地区是华东最重要的煤炭开发基地之 陈健等（2010）研究了花沟西10号煤层微量元素 一，国内学者对