属防腐蚀用水性环氧涂料及缓蚀剂的研究.pdfVIP

涂 料 Coating 金属防腐蚀用水性环氧涂料及缓蚀剂的研究 1 2 王晓艳 高延敏 孟祥玲 李国一 （1. 江苏科技大学先进焊接技术省级重点实验室，江苏镇江 212003 ；2. 扬州中集通华专用车有限公司江苏扬州225009 ） 摘 要：金属防腐蚀的方法一直是研究的热点，而水性涂料由于其无毒、无味、环保等优点也越来越受到重视。本文 选用十二烷基磺酸钠充当乳化剂，采用相反转法制备了环氧树脂乳液，研究了乳液在制备过程中乳化剂用量、乳化温度对 其平均粒径和稳定性的影响，硬脂酸盐类长链缓蚀剂作为包覆剂对具有优良性能的绢云母粉进行表面包覆改性，用扫描电 镜观察了绢云母粉包覆前后的表观形貌变化，并计算了包覆量。结论表明，将水性涂料用于金属防腐领域具有十分重要的 研究意义和应用价值。 关键词：水性环氧涂料 防腐 包覆 中图分类号：TG174.46 文献标识码：A 文章编号：1008-7818(2009)05-0025-04 Study on the Waterborne Epoxy Resin Coatings and the Corrosion Inhibitor 　　WANG Xiao-yan, GAO Yan-min, MENG Xian-ling, LI Guo-yi2 (1. Provincial Key Lab of Advanced Welding Technology,Jiangsu University of Science and Technology, Zhenjiang 212003; 2. Yangzhou CIMC Tonghua Special Vehicles Co. Ltd., Yangzhou 225009, China) Abstract: The methods of metal anti-corrosion are being studied for a long time. Waterborne paints attract so much attention due to their process non-noxious, odorless, no-harm to the environment and safe characteristic. We prepare the epoxy resin latex with SES as the emulsifier in the way of phase inversion. The influence of the emulsifier content and emulsifying temperature on average particle size and stability are investigated. The stearates, a kind of long-chain inhibitor are used to surface coat the mica powder which has good properties. The morphology of the coated and uncoated mica powder are characterized by SEM and we calculate the coated quantum. The conclusion shows that it is very valuable to research the water-based corrosion resistant coatings Key words: waterborne epoxy resin coatings ；anti-corrosion；surface coating 0 前言 量的43% ，中南美地区占25%，西欧占34%，日本占