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热解炭包覆石墨材料的研究进展 research progress of graphite coated with pyrolitic carbon
电池工业
篁!!堂篁!塑 丝兰丝丝 垫!!篁!!旦
热解炭包覆石墨材料的研究进展
王勇。杨绍斌
(辽宁工程技术大学材料系,辽宁阜新123000)
摘要:形成壳一核状复合物的热解炭包覆石墨材料不但保留了石墨的优点,而且避免了它的缺点,是
很有前景的锂离子电池负极材料。综述了热解炭包覆石墨材料的研究进展,发现,硬炭和软炭两类包
覆都使得石墨龟韫的电化学性能有提高,但是又各有优缺点;研究的焦点集中在热解炭前躯体选择,
包覆和炭化工艺的优化以及更深层次的包覆量与电化学性能的关系等几个方面。
关键词:锂离子电池;负极材料;热解炭;石墨;包覆
中国分类号:TM912.9文献标识码:A文章编号:1008—7923(2007)05—0357—04
Research of coated
with carbon
progressgraphite pyrolitic
WANG Shao—bin
Yong,YANG
and
Science T∞hnicd
(DepartmentofMaterial Engineering,Liaonlng
University,Fuxin,幽,ang123000,China)
coatedwith carbonwhichhasthestructureofcover-core
the
Abstract:Graphitepyrolitie keepsadvantages
of andovercomeits is8 anodematerialforLi·ion
graphite disadvantage.Itpromising batteries.Theresearch
on coatedwith carbonwag itws.s thatboth
progressgraphite pyrolitic summerized.Andfound hardandsoft
carbon could electrochemicalof had and
coatingimprove performancegraphitedectmde,but
advangtages
focus of
researchconcentratedonthechoiceof carbon
disadvantages.The categorypyrolitic cloth,the
of andcarbonizationandthe betweentheamountof andtheelec—
optimizationcoating relationship coating
troeh
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