磷酸酯基水性转锈防腐乳液的合成及性能研究.docVIP

磷酸酯基水性转锈防腐乳液的合成与性能研究 张光华，*徐凤 (陕西科技大学，化学与化工学院，教育部轻化工助剂化学与技术重点实验室，西安710021) 摘 要：研究了一种新型水性转化型防腐乳液，以没食子酸为原料合成有机肟类转锈剂，以P2O5为原料作为磷酸化试剂合成磷酸酯功能单体，之后采用半连续种子乳液滴加的方法乳液聚合，将具有抗闪蚀作用的磷酸酯功能单体与丙烯酸丁酯、甲基丙烯酸甲酯等进行反应，加入铁锈转化剂，制备水性带锈转锈聚合物乳液；通过扫描电镜、能谱仪、交流阻抗谱及Tafel极化曲线测试乳液涂膜对钢铁的成膜及防腐性能；结果显示转锈剂与锈蚀作用，转化为成膜物覆盖在基材表面，膜层30 min内变黑；当转锈剂用量为4%时，耐盐水腐蚀时间最长，凝胶含量最低，涂膜性能达到最佳，铁锈转化能力最强；涂膜附着力测试为1级；所制乳液涂膜硬度为H；在3.5%NaCl水溶液中浸泡72 h后涂膜几乎没有改变；不同pH条件3.5% NaCl溶液中，随pH不断增大，涂膜表现的耐腐蚀性能越好；转锈后锈层表面光滑平整、结构整齐紧密；综上，转锈效果、成膜性能良好。 关键词：水性涂料；转锈剂；没食子酸；磷酸酯 中图分类号：TQ630.7 文献标识码：A Study on the synthesis and performance research of phosphate ester base water-borne anti-corrosion emulsion ZHANG?Guang-hua,?XU Feng(Key Laboratory of Auxiliary Chemistry Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science Technology, Xi’an 710021,China） Abstract: A new type of water-based transformed anti-corrosion emulsion was researched. The organic oximes turn rust agent was synthesized by using gallic acid as raw material, and phosphate ester monomer which was a kind of applied to improve the function and properties of emulsion was synthesized by using P2O5 as phosphorylation reagent. Followed by the semi-continuous monomer dropping method. A series of water-borne anti-corrosion emulsion was prepared by phosphate functional monomer, rust agent, butyl acrylate(BA) and Methyl methacrylate (MMA) et.al. The different effect of anti-corrosion and film performance were investigated by Scanning electron microscope (SEM), Energy dispersive x-ray analysis (EDAX), Electrochemical impedance spectroscopy (EIS) and Tafel polarization curve et.al. The results showed that the rust was transformed and covered in the steel surface, the film was black at 30 min. When the amount of rust agent was 4%, the properties of anti-corrosion and film performances were excellent; the grade of coating adhesion was 1; the film almost was not changed soaked in 3.5% NaCl aqueous solution after 72h, and in different pH conditions of 3.5% NaCl solut