有机硅改性聚丙烯酸酯纳米乳液的聚合稳定性研究.pdfVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2016, 6(2), 25-32 Published Online March 2016 in Hans. /journal/hjcet /10.12677/hjcet.2016.62004 The Stability of Emulsion Polymerization for Organosiloxane Modified Acrylate Nanolatex Qingxuan Zhang, Pujiang Yang College of Science, China University of Petroleum (East China), Qingdao Shandong th th th Received: Mar. 5 , 2016; accepted: Mar. 24 , 2016; published: Mar. 30 , 2016 Copyright © 2016 by authors and Hans Publishers Inc. This work is licensed under the Creative Commons Attribution International License (CC BY). /licenses/by/4.0/ Abstract Organosiloxane modified acrylate nanolatex was synthesized by different emulsion polymeriza- tion processes with methylmethacrylate (MMA) and butylacrylate (BA) as main monomers. The effects of polymerization methods, reaction temperatures, amounts of initiator, emulsifier, vinyl- triethoxysilane (A151), 2-hydroxyethl methacrylate (HEMA), methyl acrylic acid (MAA) contents and pH on polymerization stability were investigated by measuring coagulation rate and mono- mer conversion. The results showed that with semi-continuous emulsion polymerization, organo- siloxane modified acrylate nanolatex with particle size of about 80 nm and with low coagulation rate of 0.5% as well as solid content of 40 wt% was obtained under the condition of the better reaction stability when temperature at 80˚C- 85˚C, the mass fraction of initiator, emulsifier, A151, HEMA, MAA at 0.5%, 3%, 4%, 2%, 2% respectively. The increase of emulsifier contents can im- prove the stability of the polymerization process; but the temperature increase and the