computational modelling of the hydride generation reaction in a tubular reactor and atomization in a quartz cell atomizer计算模型的氢化物生成反应在一个石英管式反应器和雾化细胞雾化器.pdfVIP

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computational modelling of the hydride generation reaction in a tubular reactor and atomization in a quartz cell atomizer计算模型的氢化物生成反应在一个石英管式反应器和雾化细胞雾化器.pdf

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computational modelling of the hydride generation reaction in a tubular reactor and atomization in a quartz cell atomizer计算模型的氢化物生成反应在一个石英管式反应器和雾化细胞雾化器

Journal of Analytical Sciences, Methods and Instrumentation, 2012, 2, 126-139 /10.4236/jasmi.2012.23022 Published Online September 2012 (http://www.SciRP.org/journal/jasmi) Computational Modelling of the Hydride Generation Reaction in a Tubular Reactor and Atomization in a Quartz Cell Atomizer Wameath S. Abdul-Majeed, William B. Zimmerman Department of Chemical and Biological Engineering, The University of Sheffield, Sheffield, UK. Email: cpp08wsa@sheffield.ac.uk, wameath@ Received May 21st, 2012; revised June 17th, 2012; accepted June 29th, 2012 ABSTRACT In this study, we present a model whereby the centre of the atomization channel is shown to be the optimal location for the spectrometric data acquisition in a quartz cell atomizer. The study aims to explore the hydride generation technique which is normally coupled with efficient thermal source to apply determination of heavy metals in water samples via spectrometric analysis. The arsenic hydride generation process and the atomization of the generated hydride in a quartz cell atomizer were studied analytically as model case studies. The hydride generation (HG) process was analyzed by adopting two hypotheses, the nascent hydrogen and formation of intermediate hydroboron species, where the results based on the second hypothesis are found to be more realistic for design purposes. Moreover, the release of the gener- ated hydride from the liquid phase and their transport to the gas phase is simulated in a helical tubular section, in which the actual tubular section length required for separation is deduced. The analytical results have been verified experi- mentally by measuring the signal intensity for the free arsenic atoms against several reaction tube lengths, in which in- creasing the tubular section length from 12 cm to 100 cm results in signal amelioration by no more than 6.6%. Further- more, the atomization of the hydride and the distribution of the generated free atoms are deduced in two c