低温固体氧化物燃料电池.ppt

Lowering the Temperature of Solid Oxide Fuel Cells 汇报人： OUTLINE Introduction of SOFC Lowering the Temperature of SOFC Impact of Anode Microstructure on SOFC SOFC 固体氧化物燃料电池(Solid Oxide Fuel Cell，简称SOFC) 是一种直接将储存在燃料和氧化剂中的化学能高效转化成电能的全固态化学发电装置。 Problem Lifetime Sealing problems Thermal expansion Start-up time Lowering the Temperature of SOFC LT-SOFC LT-SOFC（Maximum theoretical efficiency) LT-SOFC Search for new electrode and electrolyte materials. Experiment Results Conclusion The electrochemical performance of the cell was extensively improved when the size of constituent particles was reduced so as to yield a highly porous microstructure . Because of the gas diffusion, the micro-structural effect on performance occurs most clearly at higher linear fuel velocity. A zicronia-based cell could be used for a LT-SOFC system under 600℃ just by optimizing the microstructure of the an ode electrode and operating conditions References Eric D. Wachsman, Kang Taek Lee, Lowering the Temperature of Solid Oxide Fuel Cells [J]. Science, Vol. 334, No.6058, 2011, pp.935~939 Toshio Suzuki et al., Impact of Anode Microstructure on Solid Oxide Fuel Cells [J]. Science, Vol. 325,?No. 5942,?2009, ?pp. 852-855 Wei Wang et al., Progress in Solid Oxide Fuel Cells with Nickel-Based Anodes Operating on Methane and Related Fuels [J]. Chemical Reviews, Vol. 113, 2013, pp.8104~8151 * * Introduction Introduction SOFC Fuel: any fuel (from hydrogen to hydrocarbons event to carbon) High efficiency 图2 不同能量转换设备的能量密度[1] For stand-alone applications, SOFC chemical to electrical efficiency is 45 to 65%LHV, which is twice that of an internal combustion (IC) engine’s ability to convert chemical energy to mechanical work . [1] In a combined cycle, there are numerous combined heat and power (CHP) applications using SOFC systems,which have the potential to achieve efficiencies of 85% LHV. [1] [1] Eric D. Wachsman, Kang Taek Lee, Lowering the Temperature of Solid Oxide Fuel Cel