铜冶炼渣资源化利用研究进展.PDF

化 工 进 展 ·3066 · CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2017 年第 36 卷第 8 期 铜冶炼渣资源化利用研究进展 廖亚龙，叶朝，王祎洋，曹磊 （昆明理工大学冶金与能源工程学院，云南昆明 650093 ） 摘要：火法冶炼废弃渣大量露天堆存，存在铜、铁等有价金属资源未能回收利用和重金属污染土壤及水体等环 境问题。本文综述了铜火法冶炼过程中产生的典型废弃渣的物相特征，以及渣中铜、铁等有价金属回收利用的 研究现状。分析和讨论了选矿分离、湿法提取、火法贫化、高温氧化、高温还原等工艺处理铜冶炼废渣、回收 利用铜和铁的优势及存在的缺陷，展望研究趋势。分析表明：缓冷-浮选、湿法提取都能有效回收利用高品位的 冶炼铜渣，湿法酸浸中的加压浸出能抑制铁的浸出而具有应用优势；矿相资源化重构是有效利用低含量铜渣中 铜和铁资源的有效方法；在熔融态炉渣中加入氧化钙改性重构后缓冷，再进行浮选和磁选，既能回收炉渣中的 铜和铁，且浮选尾渣可以直接用于建材行业，更具备应用前景。 关键词：废物处理；反应工程；回收；冶炼渣 中图分类号：TQ09 文献标志码：A 文章编号：1000 –6613 （2017 ）08 –3066 –08 DOI ：10. 16085/j. issn. 1000-6613. 2016-2366 Resource utilization of copper smelter slag——a state-of-the-arts review LIAO Yalong ，YE Chao，WANG Yiyang，CAO Lei （Faculty of Metallurgical and Energy Engineering ，Kunming University of Science and Technology ，Kunming 650093 ， Yunnan ，China ） Abstract ：Large quantities of slag dumped in the open are contributing to the absence of recovery and utilization of valuable metals as well as potential environmental pollution to water and soil arisen by heavy metal contamination. The mineralogical characteristics and researches on recovering valuable metals from typical copper slag produced by pyrometallurgical process were summarized in the present work. The advantage and limitation of outstanding treatment methods which are presently performed to dispose of the slag for the recovery of iron and copper contained were analyzed and discussed，such as mineral separation ，hydrometallurgical extraction ，pyrometallurgical impoveri