sorption characteristics of co2 on rocks and minerals in storing co2 processes二氧化碳的吸附特征在岩石和矿物存储二氧化碳的过程.pdfVIP

Natural Resources, 2010, 1, 1-10 1 doi:10.4236/nr.2010.11001 Published Online September 2010 (http://www.SciRP.org/journal/nr) Sorption Characteristics of CO on Rocks and 2 Minerals in Storing CO2 Processes 1 1 2 2 1 Takashi Fujii , Satomi Nakagawa , Yoshiyuki Sato , Hiroshi Inomata , Toshiyuki Hashida 1Fracture and Reliability Research Institute, Tohoku University, Sendai, Japan; 2Research Center of Supercritical Fluid technology, Tohoku University, Sendai, Japan. Email: tfujii@rift.mech.tohoku.ac.jp th th st Received July 8 , 2010; revised August 18 , 2010; accepted August 31 , 2010. ABSTRACT As CO2 is injected into pore spaces of water-filled reservoir rocks, it displaces much of the pore fluids. In short terms (several to tens of years), the greater part of the injected CO is predicted to stay as free CO , i.e. in a CO rich dense 2 2 2 phase that may contain some water. This paper investigates the sorption characteristics for rocks (quartzose arenite, greywacke, shale, granite and serpentine) and minerals (quartz and albite) in the CO2 rich dense phase. The measure- ments were conducted at 50˚C and 100˚C, and pressures up to 20 MPa. Our results demonstrated that significant quan- tities of CO2 were sorbed with all the samples. Particularly, at 50˚C and 100˚C, quartzose arenite showed largest sorp- tion capacity among the other samples in higher pressures (10 MPa). Furthermore, comparison with model prediction based on