在水气界面和固体基材上沉积酞菁染料-脂肪酸膜的研究.pdfVIP

ARTICLE pubs.acs.org/JPCB Characterization of Composite PhthalocyanineFatty Acid Films from the Air/Water Interface to Solid Supports G. Giancane,*,† D. Manno,‡ A. Serra,‡ V. Sgobba,§ and L. Valli† †Dipartimento di Ingegneria dell’Innovazione, Universita degli Studi del Salento, I-73100 Lecce, Italy ‡Dipartimento di Scienze dei Materiali, Universita degli Studi del Salento, I-73100 Lecce, Italy §Department of Chemistry and Pharmacy Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-Universitat€ Erlangen-Nurnberg,€ Egerlandstrasse, 3, D-91058 Erlangen, Germany ABSTRACT: A commercial vanadyl 2,9,16,23-tetraphenoxy-29H,31H- phthalocyanine (VOPc) was dissolved in chloroform and spread on ultrapure water subphase in a Langmuir trough. The floating film was thoroughly characterized at the airwater interface by means of the Langmuir isotherm, Brewster angle microscopy, UVvis reflection spec- troscopy, and infrared measurements carried out directly at the airwater interface. All the results showed the formation of a non-uniform and aggregated floating layer, too rigid to be transferred by the Langmuir Blodgett (LB) method. For this reason, a mixture of arachidic acid and VOPc was realized, characterized, and transferred by the LB technique on solid substrates. Interface measurements and atomic force microscopy analysis suggested the formation of a uniform arachidic acid film and a superimposed VOPc placed in prone configuration. ’INTRODUCTION