氯离子传感器论文：使用环境对混凝土氯离子传感器工作性能影响.docVIP

氯离子传感器论文：使用环境对混凝土氯离子传感器工作性能的影响 【中文摘要】氯盐侵入是混凝土结构钢筋锈蚀破坏的主要因素之一，因此能够实时、准确监测混凝土中氯离子分布的电化学传感器是近年来发展起来的一种新技术。然而在实际工程中，钢筋混凝土结构会受到不同环境因素的作用，从而可能对埋入混凝土中的氯离子传感器的工作稳定性产生影响。因此，本课题以基于电化学原理的全固态氯离子传感器（以Ag/AgCl电极为工作电极，MnO2电极为参比电极）为基础，研究其埋入不同氯盐含量混凝土中的电化学性能及其在不同外界环境条件下的工作稳定性，从而为推广此技术的工程应用，为正确评估、预测实际混凝土结构受氯盐侵蚀程度提供理论依据。通过系统地研究此传感器在不同氯盐掺量的砂浆试件中的能斯特响应性能和电化学性能，研究表明：在不同氯盐掺量（1%、2%、3%）的砂浆环境中，氯离子传感器的电位输出值与氯离子浓度对数之间的线性关系与能斯特理论相吻合；恒电流极化测试中，不同氯盐掺量的砂浆中氯离子传感器的电位漂移值较大，电位恢复时间缓慢，抗极化性能较差；不同氯盐掺量的砂浆环境中的各传感器的CV曲线都存在阳极氧化峰和阴极 【英文摘要】The inducement of chloride is one of the major elements in the corrosion ofreinforced steel in concrete structures. Therefore, electrochemistry sensor appears as anewly-developed technology which can measure the distribution of chloride ion timelyand accurately in concretes in recent years. However, the structure of the reinforcedconcrete will be affected by different environmental factors in practical projects, and itis likely to influence the working stability of chloride sensor in concretes. Hence, thispaper is based on the electrochemistry-based all-solid-state concrete chloride sensor,which takes Ag/AgCl as the working electrode and MnO2 electrode as referenceelectrode, and has studied the working stability of it in different environment as well asthe electrochemistry performance of the chloride sensor in concretes of different contentof the chloride ion. Thus, it will provide the theoretical evidence for the widerapplication of the technology in projects, and supply the theoretical basis for accuratelyevaluating and predicting the level of the concrete structures which is corroded by thechloride.In this paper, the ability of Nernst response and electrochemistry performance ofthe chloride sensor has been studied systematically in the mortar of different content ofthe chlorate. The results show that, in the mortar of different content of the chloride salt（1%、2%、3%）, the linear relationship between the potential output value of the chloridesensor and the logarithm of chloride