硅藻土对污染土壤中铅的固定效果及机制的研究-中国农学通报.PDFVIP

中国农学通报 2012,28(14):240-245 Chinese Agricultural Science Bulletin 硅藻土对污染土壤中铅的固定效果及机制的研究 朱 健，王 平，李科林，雷明婧，罗文连 （中南林业科技大学环境科学与工程研究中心，长沙410004 ） 摘 要：为了有效地将硅藻土应用于土壤铅污染修复，并加以推广，逐步恢复受污染土壤的生产能力，研 究了硅藻土对污染土壤中铅的固定效果、吸附过程、等温吸附和吸附动力学。结果表明：硅藻土能充分 将土壤中交换态的铅转化为残渣态，硅藻土的施加不会对土壤pH 值和有机质等理化性质造成较大改 变；硅藻土对Pb2+ 的吸附过程控制步骤是孔道内的化学反应；硅藻土对Pb2+ 的吸附动力学属性符合伪2 级动力学模型，等温吸附符合Langmuir 模型，最大吸附量qm 为10.428 mg/g 。硅藻土可以有效固定土壤 中的铅，并降低其生物有效性，可作为铅污染土壤的有效改良剂。 关键词：硅藻土；铅；固定效果；吸附过程；等温吸附；吸附动力学 中图分类号：S156.2 ，X53 文献标志码：A 论文编号：2011-3479 Fixation Effects and Mechanisms of Diatomite on Pb in Contaminated Soil Zhu Jian, Wang Ping, Li Kelin, Lei Mingjing, Luo Wenlian (InstituteofEnvironmentalScienceandEngineeringResearch, CentralSouthUniversityofForestryTechnology, Changsha 410004) Abstract: In order to apply and extend diatomite to repair the soil polluted by lead effectively, and recover production capacity of contaminated soil step by step, fixation effect, adsorption process, isothermal adsorption and adsorption kinetics of Pb on diatomite were investigated and revealed. The results showed that, diatomite could change Pb from exchange state to residual state adequately, addition of diatomite wouldn ’t change pH and organic matter of soil, the adsorption process of Pb2 + on diatomite was mainly governed by chemical reaction in channels, the kinetic of Pb2 + adsorption on diatomite was consistent with Pseudo-second-order, the equilibrium adsorption data of Pb2 + on diatomite fitted to Langmuir isotherm, qm of Pb2 + on diatomite was 10.428 mg/g. The diatomite could fix lead in the soil effectively, and decrease its bioavailability, and was an available improver for contaminated s