二氧化碳甲烷自热重整计算分析与中试 calculation analysis and pilot test of co2-ch4 autothermal reforming.pdfVIP
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二氧化碳甲烷自热重整计算分析与中试 calculation analysis and pilot test of co2-ch4 autothermal reforming
45 6 CHEMICAL ENGINEERING OF OIL GAS 25
1 1 2 2
1 .
2 .
Gibbs (CFD)
2 4
CO ‐CH 。 ,
3
10 000 m /h、2 MPa、5 t
2
,1% 、(H )/(CO)= 1 .1、60 .7%
2 4
。 ,CO ‐CH :1 .6 m,3 .0 m,
2 .8 m,13 .8 m。
Gibbs
:TE0 :A :10 .3969/ .issn.1007‐3426 .2016 .06 .007
j
2 4
‐
, , ,
(1 . ' ‐‐ .,., 046103 , )
(2 . ‐ ,
, , 201210 ,)
2 4
:TheCO ‐CH autothermalreforming processiscalculatedandanalyzedby theGibbsfree
energy minimization methodandComputational FluidDynamics (CFD) coupledwith detailedreaction
kinetics.Combining with independent research and development reactors andcatalysts ,the pilot test
3
conditions were theraw materialgastreatmentcapacity of 10 000 m /h,operating pressureof 2 MPa,
nickel basedcatalyst loading of about 5 tons,and t
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